Bis(acyl)phosphide - Ambidentate Ligands for the Synthesis of Group 14 and 15 Main Group Element Compounds.
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DOI: 10.1002/cplu.202200451
Abstract: The reactivity of the bis(acyl)phosphide ion [P(COR)2]- (BAP-, R = Ph, Mes) with silicon halides SiX4 (X = Cl, Br) and pnictogen chlorides ECl3 (E = As, Sb and Bi) was investigated. The reaction with… read more here.
Keywords: bis acyl; ambidentate ligands; phosphide ambidentate; acyl phosphide ... See more keywords
New quinolinic derivatives as melatonergic ligands: Synthesis and pharmacological evaluation.
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DOI: 10.1016/j.ejmech.2016.12.013
Abstract: New series of melatonergic ligands issued from two methoxy-quinolinic scaffolds (2-MQ and 3-MQ), were designed and synthesized. Herein we report the synthetic scheme and pharmacological results of the new prepared compounds. Investigation of compound 11a,… read more here.
Keywords: ligands synthesis; quinolinic derivatives; synthesis pharmacological; derivatives melatonergic ... See more keywords
Hexacoppergermsesquioxanes as complexes with N-ligands: Synthesis, structure and catalytic properties
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2019.01.004
Abstract: Abstract A simple and versatile strategy of synthesis of cage metallagermaniumsesquioxanes is demonstrated for isolation of Cu6-based phenylgermsesquioxanes 1–6. Structure of newly synthesized coppergermsesquioxanes was established by single-crystal X-ray diffraction analysis. General principle of these… read more here.
Keywords: complexes ligands; hexacoppergermsesquioxanes complexes; synthesis; structure ... See more keywords
Unusual and rare pincer ligands: Synthesis, metallation, reactivity and catalytic studies
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DOI: 10.1016/j.poly.2017.07.026
Abstract: Abstract The growing interest in pincer ligand synthesis and their transition metal chemistry is due to their remarkable thermal stability to tolerate harsh reaction conditions during catalysis. In last one decade several pincer ligands have… read more here.
Keywords: pincer; ligands synthesis; chemistry; pincer ligands ... See more keywords
Fe6 clusters of tripodal alcohol ligands: Synthesis, structures and magnetostructural properties
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DOI: 10.1016/j.poly.2019.02.019
Abstract: Abstract The synthesis, crystal structures, cyclic voltammetric and magnetic characterization of (NEt3H)2[FeIII6Cl6(µ6-O)(thme)4]·3(H2O) (1) (H3thme = trishydroxymethyl ethane) and (NEt3H)2[FeIII6Cl6(µ6-O)(thmp)4]·5.5(H2O) (2) (H3thmp = trishydroxymethyl propane) are reported. Both complexes crystallized in the orthorhombic system and have the space group Pca21.… read more here.
Keywords: tripodal alcohol; synthesis; alcohol ligands; clusters tripodal ... See more keywords
{Ru(CO)x}-Core complexes with benzimidazole ligands: synthesis, X-ray structure and evaluation of anticancer activity in vivo.
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DOI: 10.1039/c6dt04295c
Abstract: The reaction of [Ru(CO)6Cl2], 1, with N[combining low line]3-methylbenzimidazole (MBI) and 5,6-dimethylbenzimidazole (DMBI) afforded two new complexes with the general formula fac-[RuII(CO)3Cl2L], L = MBI (2) or DMBI (4). Crystals of cis,trans-[RuII(CO)2Cl2(N[combining low line]3-MBI)2], 3,… read more here.
Keywords: ligands synthesis; complexes benzimidazole; core complexes; synthesis ray ... See more keywords
Molybdenum(ii) complexes with p-substituted BIAN ligands: synthesis, characterization, biological activity and computational study.
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DOI: 10.1039/c9dt00469f
Abstract: New complexes [Mo(η3-C3H5)X(CO)2(4-Y-BIAN)] (4-Y-BIAN = bis(4-Y-phenyl)-acenaphthenequinonediimine), with X = Br and Y = H, Me, OMe, COOH and X = Cl, Y = OMe, as well as the cation with X = NCMe and Y… read more here.
Keywords: synthesis characterization; complexes substituted; molybdenum complexes; bian ligands ... See more keywords