Copper complexes of 1,4-diazabutadiene ligands: Tuning of metal oxidation state and, application in catalytic C-C and C-N bond formation
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119228
Abstract: Abstract Reaction of 1,4-diazabutadiene (p-RC6H4N = C(H)(H)C = NC6H4R-p; R = OCH3, CH3, H and Cl; abbreviated as L-R) with CuCl2·2H2O in methanol at ambient temperature (25 °C) affords a group of doubly chloro-bridged dicopper complexes of type [{CuI(L-R)Cl}2], designated as 1-R.… read more here.
Keywords: copper complexes; complexes diazabutadiene; copper; ligands tuning ... See more keywords
New ruthenium compounds bearing semicarbazone 2-formylopyridine moiety: Playing with auxiliary ligands for tuning the mechanism of biological activity.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2017.07.006
Abstract: Two ruthenium(II) complexes Ru1 and Ru2 bearing as a one ligand 2,2'-bipyridine substituted by a semicarbazone 2-formylopyridine moiety (bpySC: 5-(4-{4'-methyl-[2,2'-bipyridine]-4-yl}but-1-yn-1-yl)pyridine-2-carbaldehyde semicarbazone) and as the others 2,2'-bipyridine (bpy) and 4,7-diphenyl-1,10-phenanthroline (dip), respectively, as auxiliary ligands have… read more here.
Keywords: biological activity; semicarbazone formylopyridine; ligands tuning; auxiliary ligands ... See more keywords
Game of ligands: tuning the photodynamic activity of P(V) porphyrins in aqueous media.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt00808e
Abstract: For developing novel photosensitizers (PS), three series of phosphorus(V) tetra-meso-aryl-substituted porphyrins, bearing varying numbers of pyridyl groups (0 to 2) and different axial ligands (-OH, -OEt, -OPrOH) are obtained. All complexes exhibit fluorescence in EtOH… read more here.
Keywords: tuning photodynamic; axial ligands; game ligands; ligands tuning ... See more keywords
Small molecules as ligands in the tuning of immune regulatory receptors
Sign Up to like & getrecommendations! Published in 2025 at "Frontiers in Immunology"
DOI: 10.3389/fimmu.2025.1648691
Abstract: Professional antigen-presenting cells (APCs) represent a crucial link between the innate and the adaptive immune response. APCs express specific surface receptors which are primarily involved in “non-self” and/or “self” ligand recognition. Upon ligand binding, these… read more here.
Keywords: tuning immune; regulatory receptors; immune regulatory; ligands tuning ... See more keywords