Influence of Thiolate versus Alkoxide Ligands on the Stability of Crystallographically Characterized Mn(III)-Alkylperoxo Complexes.
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DOI: 10.1021/jacs.0c13001
Abstract: The work described herein demonstrates the exquisite control that the inner coordination sphere of metalloenzymes and transition-metal complexes can have on reactivity. We report one of few crystallographically characterized Mn-peroxo complexes and show that the… read more here.
Keywords: iii oor; thiolate ligated; crystallographically characterized; ligated iii ... See more keywords