Direct Reduction of NO to N2O by a Mononuclear Nonheme Thiolate Ligated Iron(II) Complex via Formation of a Metastable {FeNO}7 Complex.
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DOI: 10.1021/acs.inorgchem.2c02383
Abstract: Addition of NO to a nonheme dithiolate-ligated iron(II) complex, FeII(Me3TACN)(S2SiMe2) (1), results in the generation of N2O. Low-temperature spectroscopic studies reveal a metastable six-coordinate {FeNO}7 intermediate (S = 3/2) that was trapped at -135 °C… read more here.
Keywords: thiolate ligated; ligated iron; reduction n2o; iron complex ... See more keywords
Enhanced Reactivity through Equatorial Sulfur Coordination in Nonheme Iron(IV)-Oxo Complexes: Insights from Experiment and Theory.
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DOI: 10.1021/acs.inorgchem.4c00070
Abstract: Sulfur ligation in metalloenzymes often gives the active site unique properties, whether it is the axial cysteinate ligand in the cytochrome P450s or the equatorial sulfur/thiol ligation in nonheme iron enzymes. To understand sulfur ligation… read more here.
Keywords: oxo complexes; iron; iron oxo; nonheme iron ... See more keywords
Anilido-Oxazoline-Ligated Iron Alkoxide Complexes for Living Ring-Opening Polymerization of Cyclic Esters with Controllability.
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DOI: 10.1021/acs.inorgchem.4c04028
Abstract: Anilido-oxazoline-ligated iron complexes, including bis(anilido-oxazolinate) iron(II), mononuclear iron(II) alkyl and aryloxide, as well as the dinuclear analogues, were synthesized, and their catalytic performance on ring-opening polymerization (ROP) has been studied. Transmetalation of FeCl2(THF)1.5 with in… read more here.
Keywords: anilido oxazolinate; iron; ring opening; anilido oxazoline ... See more keywords