Investigation of the Deprotonative Generation and Borylation of Diamine-Ligated α-Lithiated Carbamates and Benzoates by in Situ IR spectroscopy.
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DOI: 10.1021/jacs.8b06871
Abstract: Diamine-mediated α-deprotonation of O-alkyl carbamates or benzoates with alkyllithium reagents, trapping of the carbanion with organoboron compounds, and 1,2-metalate rearrangement of the resulting boronate complex are the primary steps by which organoboron compounds can be… read more here.
Keywords: diamine ligated; situ spectroscopy; ligated lithiated; carbamates benzoates ... See more keywords