Evidence for regioselective Pt(II)-mediated hydroxylation of long linear alkanes in acetic acid
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Catalysis"
DOI: 10.1016/j.jcat.2018.10.020
Abstract: Abstract Selective functionalization of hydrocarbons remains one of the most challenging reactions in organic chemistry. With respect to terminal C H hydroxylation, electrophilic activation by late transition metals has been considered a promising route. We… read more here.
Keywords: hydroxylation; chemistry; evidence; linear alkanes ... See more keywords
Chemical Ionization of Large Linear Alkanes and Small Oxidized Volatile Organic Compounds by the Reactions with Atomic Gold Cations.
Sign Up to like & getrecommendations! Published in 2017 at "Analytical chemistry"
DOI: 10.1021/acs.analchem.7b01791
Abstract: Although the use of proton-transfer-reaction mass spectrometry (PTR-MS) in real-time measurements of atmospheric volatile organic compounds (VOCs) has expanded rapidly in recent years, PTR-MS has several serious limitations related to H3O+ reagent ion chemistry, such… read more here.
Keywords: organic compounds; small oxidized; volatile organic; chemistry ... See more keywords
Oxidation Behavior and Kinetics of Eight C20–C54 n-Alkanes by High Pressure Differential Scanning Calorimetry (HP-DSC)
Sign Up to like & getrecommendations! Published in 2018 at "Energy & Fuels"
DOI: 10.1021/acs.energyfuels.8b01401
Abstract: In this study, the oxidation behavior and kinetics of linear alkanes (C20H42, C24H50, C30H62, C32H66, C36H74, C38H78, C50H102, and C54H110) were investigated by high pressure differential scanning calorimetry (HP-DSC). It turned out that only the… read more here.
Keywords: oxidation; behavior kinetics; linear alkanes; high pressure ... See more keywords
Efficient Mechanochemical Synthesis of MOF-5 for Linear Alkanes Adsorption
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Chemical & Engineering Data"
DOI: 10.1021/acs.jced.7b00049
Abstract: An efficient mechanochemical method was proposed to synthesize MOF-5 with high BET area within minutes. The effects of parameters such as solvents activation, the metal/ligand ratio, grinding speed and time were carefully studied and the… read more here.
Keywords: adsorption; synthesis mof; mof; linear alkanes ... See more keywords
Hydration of Linear Alkanes is Governed by the Small Length-Scale Hydrophobic Effect.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of chemical theory and computation"
DOI: 10.1021/acs.jctc.2c00219
Abstract: Length-scale dependence of the hydrophobic effect is well understood for apolar spherical solutes: for small solutes (diameter, d ≲ 0.8 nm), the hydration free energy is entropically driven, while for larger solutes (d ≳ 2… read more here.
Keywords: linear alkanes; hydrophobic effect; length scale;