Understanding the Relationship between Catalytic Activity and Termination in photoATRP: Synthesis of Linear and Bottlebrush Polyacrylates
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02397
Abstract: Linear and bottlebrush polyacrylates were prepared by photomediated atom transfer radical polymerization (photoATRP) catalyzed by either CuBr2/TPMA (tris(2-pyridylmethyl)amine) or the more active C... read more here.
Keywords: bottlebrush polyacrylates; linear bottlebrush; understanding relationship; photoatrp ... See more keywords
Synthesis of well-defined linear–bottlebrush–linear triblock copolymer towards architecturally-tunable soft materials
Sign Up to like & getrecommendations! Published in 2022 at "Polymer Chemistry"
DOI: 10.1039/d2py00841f
Abstract: Linear–bottlebrush–linear (LBBL) triblock copolymers are emerging systems for topologically-tunable elastic materials. In this paper, a new synthetic methodology is presented to synthesize LBBL polystyrene-block-bottlebrushpolydimethylsiloxane-block-polystyrene (PS-b-bbPDMS-b-PS) triblock copolymer via the “grafting onto” approach where the precursors… read more here.
Keywords: copolymer; bottlebrush linear; triblock copolymer; linear bottlebrush ... See more keywords