Adjustable chiral self-sorting and self-discriminating behaviour between diamond-like Tröger's base-linked cryptands.
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DOI: 10.1039/c9cc03577j
Abstract: Two isomers of Tröger's base-linked cryptands 5a and 5b were synthesized, and both of them have two chiral N-centers, exhibiting rare diamond-like scaffolds. Particularly, when growing from the solution of rac-5a, a single enantiomer RNRN-5a… read more here.
Keywords: linked cryptands; base linked; ger base; chiral self ... See more keywords