Linker permethylation as a means to foster valence tautomerism and thwart dimerization in ferrocenyl-triarylmethylium cations.
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DOI: 10.1039/d3dt00857f
Abstract: Permethylation of the phenylene linker in a cationic ferrocenyl-phenylthioxanthylium dyad increases the amount of the diradical ferrocenium thioxanthyl radical valence tautomer and aids in supressing dimerization of the latter and of the one-electron reduced neutral… read more here.
Keywords: permethylation; dimerization; linker permethylation; ferrocenyl ... See more keywords