Dynamic Kinetic Resolution of 2‐Hydroxybiaryl Atropisomers via Lipase‐Catalyzed Enantioselective O‐Acylation
Sign Up to like & getrecommendations! Published in 2024 at "ChemCatChem"
DOI: 10.1002/cctc.202400932
Abstract: The increasing interest in axially chiral biaryl moieties, which are prevalent in chiral ligands, organocatalysts, and bioactive molecules, has raised the need for developing novel efficient synthetic methods for these types of molecules. In addition… read more here.
Keywords: dynamic kinetic; enantioselective acylation; lipase catalyzed; resolution ... See more keywords
Lipase-catalyzed enantioselective transesterification of prochiral 1-((1,3-dihydroxypropan-2-yloxy)methyl)-5,6,7,8-tetrahydroquinazoline-2,4(1H,3H)-dione in ionic liquids.
Sign Up to like & getrecommendations! Published in 2018 at "Chirality"
DOI: 10.1002/chir.22787
Abstract: The application of ionic liquids as solvents for transesterification of prochiral pirymidine acyclonucleoside using lipase (EC 3.1.1.3) Amano PS from Burkholderia cepacia (BCL) is reported. The effect of using medium reaction, acyl group donor, and… read more here.
Keywords: lipase catalyzed; bmim pf6; catalyzed enantioselective; transesterification prochiral ... See more keywords
Resolution of (R,S)-1-(4-methoxyphenyl)ethanol by lipase-catalyzed stereoselective transesterification and the process optimization.
Sign Up to like & getrecommendations! Published in 2021 at "Chirality"
DOI: 10.1002/chir.23402
Abstract: An efficient lipase-catalyzed stereoselective transesterification reaction system was established for resolution of 1-(4-methoxyphenyl)ethanol (MOPE) enantiomers. A series of lipases were tested and compared. The immobilized lipase Novozym 40086 is selected as the best choice. The… read more here.
Keywords: lipase; methoxyphenyl ethanol; stereoselective transesterification; catalyzed stereoselective ... See more keywords
Activation of Lipase-Catalyzed Reactions Using Ionic Liquids for Organic Synthesis.
Sign Up to like & getrecommendations! Published in 2018 at "Advances in biochemical engineering/biotechnology"
DOI: 10.1007/10_2018_62
Abstract: The use of ionic liquids to replace organic or aqueous solvents in biocatalysis processes has recently received great attention, and much progress has been made in this area; the lipase-catalyzed reactions are the most successful.… read more here.
Keywords: ionic liquids; lipase catalyzed; catalyzed reactions; organic synthesis ... See more keywords
Lipase-catalyzed synthesis of biodiesel from black soldier fly (Hermetica illucens): Optimization by using response surface methodology
Sign Up to like & getrecommendations! Published in 2017 at "Energy Conversion and Management"
DOI: 10.1016/j.enconman.2017.05.010
Abstract: Abstract Black soldier fly larvae (BSFL), oleaginous insects, can assimilate several organic wastes for fat accumulation, thus serving as a promising feedstock for biodiesel production. In this study, the transesterification of BSFL fat and methanol… read more here.
Keywords: methodology; lipase catalyzed; biodiesel; black soldier ... See more keywords
Lipase-Catalyzed Synthesis of Sn-2 Palmitate: A Review
Sign Up to like & getrecommendations! Published in 2020 at "Engineering"
DOI: 10.1016/j.eng.2020.02.008
Abstract: Abstract Human milk fat (HMF) is an important source of nutrients and energy for infants. Triacylglycerols (TAGs) account for about 98% of HMF and have a unique molecular structure. HMF is highly enriched in palmitic… read more here.
Keywords: lipase catalyzed; palmitate; hmf; synthesis palmitate ... See more keywords
Chemoenzymatic enantioselective and stereo-convergent syntheses of lisofylline enantiomers via lipase-catalyzed kinetic resolution and optical inversion approach
Sign Up to like & getrecommendations! Published in 2021 at "Molecular Catalysis"
DOI: 10.1016/j.mcat.2021.111451
Abstract: Abstract Highly enantioselective enzymatic kinetic resolution (EKR) of racemic lisofylline is presented for the first time. A comprehensive optimization of the key parameters of lipase-catalyzed transesterification of racemic lisofylline revealed that optimal biocatalytic system consisted… read more here.
Keywords: resolution; kinetic resolution; catalyzed kinetic; racemic lisofylline ... See more keywords
Immobilized lipase-catalyzed esterification for synthesis of trimethylolpropane triester as a biolubricant
Sign Up to like & getrecommendations! Published in 2019 at "Renewable Energy"
DOI: 10.1016/j.renene.2018.06.092
Abstract: Abstract Synthetic oleochemical esters of polyols and fatty acids are biodegradable and possess desirable technical and ecological properties. Trimethylolpropane (TMP) triester has been widely applied as a hydraulic fluid. TMP triester was effectively synthesized by… read more here.
Keywords: triester; immobilized lipase; lipase; tmp triester ... See more keywords
Review on Lipase-Catalyzed Flavor Synthesis: Global Trends and Advances
Sign Up to like & getrecommendations! Published in 2025 at "Journal of Agricultural and Food Chemistry"
DOI: 10.1021/acs.jafc.5c00386
Abstract: The enzymatic synthesis of esterified flavors is pivotal in the food, pharmaceutical, and cosmetic industries. Among the available approaches, lipase-catalyzed reactions have gained increasing attention due to the enzymes’ biodegradability, high enantio- and regioselectivity, availability,… read more here.
Keywords: chemistry; lipase catalyzed; flavor synthesis; synthesis ... See more keywords
Lipase-Catalyzed Synthesis and Biological Evaluation of N-Picolineamides as Trypanosoma cruzi Antiproliferative Agents.
Sign Up to like & getrecommendations! Published in 2023 at "ACS medicinal chemistry letters"
DOI: 10.1021/acsmedchemlett.2c00425
Abstract: In our search for new safe antiparasitic agents, an enzymatic pathway was applied to synthesize a series of N-pyridinylmethyl amides derived from structurally different carboxylic acids. Thirty derivatives, including 11 new compounds, were prepared through… read more here.
Keywords: synthesis biological; lipase catalyzed; biological evaluation; antiproliferative agents ... See more keywords
Green Formulation Strategy for Preparing Oil-in-Water Emulsions via Lipase-Catalyzed Transesterification
Sign Up to like & getrecommendations! Published in 2017 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.6b02688
Abstract: Formulation of submicronic diglyceride-in-water emulsions was carried out without addition of synthetic surfactant in case of commercial caprylic/capric diglyceride. Sugar surfactant was prepared by contacting the oil with a concentrated aqueous solution of sorbitol (70… read more here.
Keywords: lipase catalyzed; preparing oil; catalyzed transesterification; water ... See more keywords