Lipase-mediated regioselective modifications of macrolactonic sophorolipids
Sign Up to like & getrecommendations! Published in 2017 at "Tetrahedron"
DOI: 10.1016/j.tet.2017.02.043
Abstract: Abstract Chemoenzymatic synthesis and modification of well-defined macrolactonic sophorolipid (SLML) analogues via a series of successive regioselective de-esterification/transesterification reactions is investigated. Of the lipases screened, Candida antartica lipase- B (Novozyme-435) successfully deacylated the C-6′ acetoxy… read more here.
Keywords: lipase mediated; regioselective modifications; mediated regioselective; macrolactonic sophorolipids ... See more keywords
Lipase-Mediated Kinetic Resolution: An Introductory Approach to Practical Biocatalysis
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DOI: 10.1021/acs.jchemed.6b00606
Abstract: An experimental protocol that provides an excellent way to discuss concepts at the crossroads of organic chemistry and biochemistry employing biocatalysis is presented. By evaluating several reaction parameters (enzyme source, organic solvent, and acyl donor),… read more here.
Keywords: biochemistry; lipase mediated; biocatalysis; chemistry ... See more keywords
Lipase-Mediated Mechanoenzymatic Synthesis of Sugar Esters in Dissolved Unconventional and Neat Reaction Systems
Sign Up to like & getrecommendations! Published in 2022 at "ACS Sustainable Chemistry & Engineering"
DOI: 10.1021/acssuschemeng.2c01727
Abstract: Mechanochemical and biocatalytic approaches in modern research are two major assets to develop greener processes. In the present study, these modular tools of sustainability are pointed toward the production of versatile and daily employed compounds… read more here.
Keywords: reaction; synthesis; reaction systems; mechanoenzymatic synthesis ... See more keywords
Lipase mediated synthesis of polycaprolactone and its silica nanohybrid
Sign Up to like & getrecommendations! Published in 2019 at "Pure and Applied Chemistry"
DOI: 10.1515/pac-2018-1011
Abstract: Abstract In this study, rice husk ash (RHA) silanized with 3-glycidyloxypropyl trimethoxysilane was used as support material to immobilize Candida antarctica lipase B. The developed biocatalyst was then utilized in the ring opening polymerization (ROP)… read more here.
Keywords: lipase mediated; synthesis polycaprolactone; lipase; silica nanohybrid ... See more keywords