Lipase/Oxovanadium Co-Catalyzed Dynamic Kinetic Resolution of Propargyl Alcohols: Competition between Racemization and Rearrangement.
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DOI: 10.1021/acs.orglett.9b00334
Abstract: Quantitative conversion of racemic propargyl alcohols into optically active propargyl esters with up to 99% ee has been achieved by lipase/oxovanadium co-catalyzed dynamic kinetic resolution, which combines the lipase-catalyzed enantioselective esterification of the racemic substrates… read more here.
Keywords: lipase oxovanadium; racemization; propargyl alcohols; oxovanadium catalyzed ... See more keywords