The Dependence of Ionic Liquid Solvent Effects on the Nucleophilic Heteroatom in SN Ar Reactions. Highlighting the Potential for Control of Selectivity.
Sign Up to like & getrecommendations! Published in 2019 at "ChemPlusChem"
DOI: 10.1002/cplu.201900173
Abstract: Nucleophilic aromatic substitution (SN Ar) reactions of 1-fluoro-4-nitrobenzene using similar nitrogen and sulfur nucleophiles were studied through extensive kinetic analysis in mixtures containing ionic liquids. The interactions of the ionic liquid components with the starting… read more here.
Keywords: solvent effects; effects nucleophilic; ionic liquid; liquid ... See more keywords
Preparation of novel, liquid, solvent‐free, polyolefin‐based adhesives
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DOI: 10.1002/pat.4826
Abstract: An innovative approach for functionalization of polyolefins was developed and newfound polyolefins end-capped with trimethoxysilane (silylated polyolefins) was discovered as a material which can be applicable as an extraordinary polyolefin-based adhesive. For synthesizing mentioned materials,… read more here.
Keywords: preparation novel; polyolefin based; liquid solvent; novel liquid ... See more keywords
Switching the Structural Force in Ionic Liquid-Solvent Mixtures by Varying Composition.
Sign Up to like & getrecommendations! Published in 2017 at "Physical review letters"
DOI: 10.1103/physrevlett.118.096002
Abstract: The structure and interactions in electrolytes at high concentration have implications from energy storage to biomolecular interactions. However, many experimental observations are yet to be explained in these mixtures, which are far beyond the regime… read more here.
Keywords: ionic liquid; liquid; switching structural; liquid solvent ... See more keywords