Monitoring an ionic liquid synthesis with in-situ IR-spectroscopy – The intricacy of solvent effects
Sign Up to like & getrecommendations! Published in 2019 at "Chemical Engineering Journal"
DOI: 10.1016/j.cej.2019.02.195
Abstract: Abstract This work focuses on the ionic liquid (IL) synthesis starting from dimethyl carbonate and 1-ethylimidazole in methanol. In-situ IR-spectroscopy is used to gain time-dependent concentrations for kinetic analysis. The reaction is found to be… read more here.
Keywords: spectroscopy; ionic liquid; reaction; reaction rate ... See more keywords
Bimetallic Co/Al nanoparticles in an ionic liquid: synthesis and application in alkyne hydrogenation
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj03622a
Abstract: CoAl- and Co3Al-NPs are effective catalysts for alkyne-to-alkane hydrogenation with DIBAL-H as a co-catalyst under mild conditions (2 bar H2, 30 °C). read more here.
Keywords: ionic liquid; nanoparticles ionic; liquid synthesis; hydrogenation ... See more keywords