Elucidation of the role of lithium iodide as an additive for the liquid‐based synthesis of Li7P2S8I solid electrolyte
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DOI: 10.1002/er.5775
Abstract: Liquid‐phase synthesis for a sulfide‐based solid electrolyte has been widely studied due to its great advantage of being a simpler and more cost‐effective method compared with the conventional solid‐phase synthesis, even it could induce homogeneous… read more here.
Keywords: solid electrolyte; additive liquid; synthesis; role ... See more keywords
Improved ionic conductivity and battery function in a lithium iodide solid electrolyte via particle size modification
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DOI: 10.1016/j.electacta.2021.138569
Abstract: Abstract Solid electrolytes (SEs) are a promising, safe alternative to liquid electrolytes in high energy density batteries, but low conductivity issues remain a challenge. Herein, a lithium iodide based solid electrolyte (SE) was improved by… read more here.
Keywords: conductivity; particle size; lithium iodide;
Triphenylphosphine-Catalyzed Alkylative Iododecarboxylation with Lithium Iodide under Visible Light.
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DOI: 10.1021/acs.orglett.0c03173
Abstract: Under irradiation of 456 nm blue light-emitting diodes, PPh3 catalyzes the iododecarboxylation of aliphatic carboxylic acid derived N-(acyloxy)phthalimide with lithium iodide as an iodine source. The reaction delivers primary, secondary, and bridgehead tertiary alkyl iodides… read more here.
Keywords: triphenylphosphine catalyzed; lithium iodide; catalyzed alkylative; iododecarboxylation ... See more keywords
Palladium(0)-Lithium Iodide Cocatalyzed Asymmetric Hydroalkylation of Conjugated Enynes with Pronucleophiles Leading to 1,3-Disubstituted Allenes.
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DOI: 10.1021/acs.orglett.9b02439
Abstract: Axially chiral 1,3-disubstituted allenes were synthesized via hydroalkylation of alkyl- or aryl-substituted conjugated enynes (readily prepared via a Sonogashira reaction) with pronucleophiles such as dimethyl malonate under the cocatalysis of DTBM-SEGPHOS-ligated palladium and lithium iodide.… read more here.
Keywords: disubstituted allenes; lithium iodide; conjugated enynes; palladium lithium ... See more keywords