End-Capping Reaction of Living Anionic Poly(benzyl methacrylate) with a Pentafluorophenyl Ester for a Norbornenyl-ω-End Macromonomer with a Long Flexible Spacer: Advantage in the Well-Controlled Synthesis of Ultrahigh-Molecular-Weight Bottlebrush Polymers
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b00559
Abstract: 12-(cis-5-Norbornene-exo-2,3-dicarboximido)dodecanoate pentafluorophenyl ester (exo-NBC12-PFP) was used as a norbornene-substituted end-capping terminator of living anionic polymers. Polystyrene wi... read more here.
Keywords: pentafluorophenyl ester; living anionic; end capping;
Precision Synthesis of Polypeptides via Living Anionic Ring-Opening Polymerization of N-Carboxyanhydrides by Tri-thiourea Catalysts.
Sign Up to like & getrecommendations! Published in 2022 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.2c10950
Abstract: The chemistry of α-amino acid N-carboxyanhydrides (NCAs) has a history of over 100 years, but precise and efficient ring-opening polymerization methods for NCAs remain highly needed to facilitate the studies of polypeptides─that is, mimics of… read more here.
Keywords: living anionic; tri thiourea; anionic ring; opening polymerization ... See more keywords
Hairy Particles Synthesized by Living Anionic Polymerization-induced Self-assembly and Evaluation of Their Nanostructure
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DOI: 10.1246/cl.200957
Abstract: Hairy particles consisting of polyisoprene-b-polystyrene (PI-b-PS) were synthesized by polymerization-induced self-assembly (PISA) based on living anionic polymerization method. The molecular aggre... read more here.
Keywords: induced self; living anionic; hairy particles; polymerization induced ... See more keywords
1,3-Pentadiene-Assistant Living Anionic Terpolymerization: Composition Impact on Kinetics and Microstructure Sequence Primary Analysis
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DOI: 10.3390/polym15092191
Abstract: The combination of a living anionic technology and a unique alternating strategy provided an exciting opportunity to prepare novel and well-defined poly(1,3-pentadiene-co-syrene-co-1,1-diphenylethylene) resins consisting of three alternating sequences of modules (A/B/C zwitterions). “A” being Styrene… read more here.
Keywords: terpolymerization; living anionic; composition; analysis ... See more keywords