Synthesis of Highly Defined Graft Copolymers Using a Cyclic Acetal Moiety as a Two-Stage Latent Initiating Site for Successive Living Cationic Polymerization and Ring-Opening Anionic Polymerization
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DOI: 10.1021/acs.macromol.7b02622
Abstract: The synthesis of well-defined graft copolymers with designed intervals between branches was achieved using cyclic acetal moieties as two-stage latent initiating sites. A cyclic acetal was shown to initiate the living cationic polymerization of vinyl… read more here.
Keywords: cyclic acetal; cationic polymerization; polymerization; graft copolymers ... See more keywords
R–Cl/SnCl4/n-Bu4NCl-induced direct living cationic polymerization of naturally-derived unprotected 4-vinylphenol, 4-vinylguaiacol, and 4-vinylcatechol in CH3CN
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DOI: 10.1039/c8py01831f
Abstract: A R–Cl/SnCl4/n-Bu4NCl-initiating system induced direct living cationic polymerization of naturally derived styrene monomers with phenol and catechol groups in CH3CN. read more here.
Keywords: living cationic; direct living; induced direct; polymerization naturally ... See more keywords