l-lactide polymerization – living and controlled – catalyzed by initiators: Hydroxyalkylated organic bases
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DOI: 10.1016/j.polymer.2016.11.070
Abstract: Abstract Polymerizations of l -lactide (LA) were initiated with hydroxyalkylated strong organic bases functioning simultaneously as catalysts (INICATs). Organocatalysts used until now in Ring-Opening Polymerization, particularly of l -lactide, had to be combined with separately… read more here.
Keywords: organic bases; lactide polymerization; polymerization; polymerization living ... See more keywords
Visible light-induced living/controlled cationic ring-opening polymerization of lactones
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DOI: 10.1038/s41428-020-0394-x
Abstract: Ring-opening polymerization of lactones has served as one of the most resourceful and versatile methods for the production of polyesters. However, the photocontrolled ring-opening polymerization of lactones with the advantages of being inexpensive, green, and… read more here.
Keywords: ring opening; polymerization; opening polymerization; controlled cationic ... See more keywords
Phosphonium Ylide/Organoaluminum-Based Lewis Pairs for the Highly Efficient Living/Controlled Polymerization of Alkyl (Meth)acrylates
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DOI: 10.1039/d3py00301a
Abstract: The development of living/controlled polymerization technologies is of great interest in both fundamental study and industrial application. Herein, we report on the use of easily synthesized phosphonium ylides Ph3P=CR1R2 (R1,R2... read more here.
Keywords: ylide organoaluminum; phosphonium ylide; living controlled; controlled polymerization ... See more keywords