Synthesis of High Molecular Weight Polymers by Organocatalyzed Living Radical Polymerization and Self-assembly.
Sign Up to like & getrecommendations! Published in 2023 at "Macromolecular rapid communications"
DOI: 10.1002/marc.202300005
Abstract: A mild organocatalyzed living radical polymerization method was studied for high molecular weight polymers (HMWPs), yielding low-dispersity linear and star polymers (Đ = Mw /Mn = 1.03-1.28) up to Mn = 3.9 × 105 and monomer… read more here.
Keywords: radical polymerization; molecular weight; living radical; high molecular ... See more keywords
Single-Electron Transfer Living Radical Polymerization Platform to Practice, Develop, and Invent.
Sign Up to like & getrecommendations! Published in 2017 at "Biomacromolecules"
DOI: 10.1021/acs.biomac.7b01131
Abstract: The most fundamental aspects of single-electron transfer (SET) principles are presented. They are discussed according to different definitions used by expert practitioners and are applied to SET living radical polymerization (SET-LRP) according to the definition… read more here.
Keywords: polymerization; single electron; radical polymerization; living radical ... See more keywords
50th Anniversary Perspective: Metal-Catalyzed Living Radical Polymerization: Discovery and Perspective
Sign Up to like & getrecommendations! Published in 2017 at "Macromolecules"
DOI: 10.1021/acs.macromol.6b02711
Abstract: Development of living polymerizations via reversible activation of dormant species opened the door to discovery of metal-catalyzed living radical polymerization that is now very useful for precise construction of tailor-made polymeric architectures. In this commemorative… read more here.
Keywords: polymerization; radical polymerization; living radical; metal catalyzed ... See more keywords
Fluorous Gradient Copolymers via in-Situ Transesterification of a Perfluoromethacrylate in Tandem Living Radical Polymerization: Precision Synthesis and Physical Properties
Sign Up to like & getrecommendations! Published in 2018 at "Macromolecules"
DOI: 10.1021/acs.macromol.7b02512
Abstract: Perfluorinated gradient copolymers comprising fluorous units and hydrophobic or hydrophilic units were created as fluorous polymer materials with unique physical properties. The gradient copolymers were efficiently synthesized via the tandem catalysis of living radical polymerization… read more here.
Keywords: polymerization; radical polymerization; transesterification; physical properties ... See more keywords
Recyclable Solid-Supported Catalysts for Quaternary Ammonium Iodide-Catalyzed Living Radical Polymerization
Sign Up to like & getrecommendations! Published in 2019 at "Macromolecules"
DOI: 10.1021/acs.macromol.9b02266
Abstract: Quaternary ammonium iodide (R4N+I–) catalysts immobilized on silica particles, Fe3O4 magnetic particles, and organic resin particles were developed for organocatalyzed living radical polymerization... read more here.
Keywords: quaternary ammonium; living radical; ammonium iodide; radical polymerization ... See more keywords
One-pot synthesis for gradient copolymers via concurrent tandem living radical polymerization: mild and selective transesterification of methyl acrylate through Al(acac)3 with common alcohols
Sign Up to like & getrecommendations! Published in 2021 at "RSC Advances"
DOI: 10.1039/d1ra04595d
Abstract: The acrylate based gradient copolymers were successfully synthesized by concurrent tandem living radical polymerization using Al(acac)3 as cocatalyst with common alcohols. read more here.
Keywords: concurrent tandem; radical polymerization; living radical; gradient copolymers ... See more keywords