All-inorganic open frameworks based on gigantic four-shell Ln@W8@Ln8@(SiW12)6 clusters.
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DOI: 10.1039/d0cc04070c
Abstract: A series of POM-based all-inorganic open frameworks, H9[Ln9W8(μ4-O)12(μ2-O)24(H2O)24](SiW12O40)3·60H2O (1-Ln, Ln = La, Pr and Nd), have been fabricated and structurally characterized for the first time. The unique architectures are constructed from nanoscale four-shell Ln@W8@Ln8@(SiW12)6 clusters.… read more here.
Keywords: inorganic open; four shell; siw12 clusters; ln8 siw12 ... See more keywords