Catalytic asymmetric synthesis of carboranylated diols bearing two adjacent stereocenters located at the α,β-position of o-carborane cage carbon.
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DOI: 10.1039/d3dt00129f
Abstract: Despite the great interest in carborane-containing molecules, there is a lack of literature on the generation of central chiralities, via catalytic asymmetric transformations using prochiral carboranyl substrates. Herein, we have synthesized novel optically active icosahedral… read more here.
Keywords: adjacent stereocenters; two adjacent; located position; carborane ... See more keywords