Synthesis, Structure, and Reductive Elimination of Cationic Monoarylpalladium(IV) Complexes Supported by a Tripodal Oxygen Ligand
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DOI: 10.1002/ejic.201700326
Abstract: Cationic monoaryl–PdIV complexes supported by the Klaui tripodal ligand [Co(η5-C5H5){P(O)(OEt)2}3]– (LOEt–) were synthesized, and their reductive elimination was studied. Treatment of trans-[Pd(PPh3)2(Ar)(I)] and [{Pd(η2-ppytBu)Cl}2] [ppytBuH = 2-(4-tert-butylphenyl)pyridine] with [AgLOEt] afforded [Pd(Ar)(PPh3)(η2-LOEt)] [Ar = Ph (1),… read more here.
Keywords: complexes supported; loet; elimination; loet pf6 ... See more keywords
Reactions of cerium complexes with transition metal nitrides: synthesis and structure of heterometallic cerium complexes containing bridging catecholate ligands.
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DOI: 10.1039/c9dt02959a
Abstract: In an attempt to synthesize heterometallic cerium nitrido complexes, we studied the reactions of cerium complexes supported by the Kläui tripodal ligand [Co(η5-C5H5){PO(OEt)2}3]- (LOEt-) with transition-metal nitrides. Whereas no reactions were found between Ce-LOEt complexes… read more here.
Keywords: reactions cerium; cerium complexes; heterometallic cerium; loet ... See more keywords