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   Articles with "lossen rearrangement" as a keyword



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Synthesis of Nε‐acetyl‐L‐homolysine by the Lossen rearrangement and its application for probing deacetylases and binding modules of acetyl‐lysine

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recommendations! Published in 2022 at "Journal of Peptide Science"

DOI: 10.1002/psc.3462

Abstract: Lysine acetylation is a posttranslational protein modification mediating protein–protein interactions by recruitment of bromodomains. Investigations of bromodomains have focused so far on the sequence context of the modification site and acyl‐modifications installed at lysine side… read more here.

Keywords: lossen rearrangement; synthesis acetyl; acetyl homolysine; acetyl lysine ... See more keywords
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Lossen Rearrangement vs C-N Reductive Elimination Enabled by Rh(III)-Catalyzed C-H Activation/Selective Lactone Ring-Opening: Chemodivergent Synthesis of Quinolinones and Dihydroisoquinolinones.

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recommendations! Published in 2020 at "Organic letters"

DOI: 10.1021/acs.orglett.0c03734

Abstract: An unprecedented Rh(III)-catalyzed cascade C-H activation/Lossen rearrangement of aromatic amides with methyleneoxetanones has been realized along with a tunable C-N bond reductive elimination/trans esterification, giving divergent access to quinolinones and dihydroisoquinolinones via selective ring-opening of… read more here.

Keywords: ring opening; lossen rearrangement; iii catalyzed; activation ... See more keywords
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Synthesis and application of thiocarbamates via thiol-dioxazolone modified Lossen rearrangement.

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recommendations! Published in 2022 at "Chemical communications"

DOI: 10.1039/d2cc05198b

Abstract: Thiocarbamates could be synthesized in green solvents via thiol-dioxazolone modified Lossen rearrangement under transition-metal free, additive free, and mild conditions. Polythiocarbamates were further prepared with excellent self-healing and shape-memory properties, showing great potential in the… read more here.

Keywords: lossen rearrangement; dioxazolone modified; thiol dioxazolone; modified lossen ... See more keywords