Low-Coordinate Erbium(III) Single-Molecule Magnets with Photochromic Behavior
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic Chemistry"
DOI: 10.1021/acs.inorgchem.2c01999
Abstract: The structures and magnetic properties of photoresponsive magnets can be controlled or fine-tuned by visible light irradiation, which makes them appealing as candidates for ternary memory devices: photochromic and photomagnetic at the same time. One… read more here.
Keywords: low coordinate; single molecule; molecule magnets; erbium iii ... See more keywords
Low-Coordinate Iron Hydride Chemistry at an N,N,C-Heteroscorpionate Platform
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DOI: 10.1021/acs.inorgchem.4c01596
Abstract: Locally high-spin iron hydrides are proposed to play a critical role as intermediates in iron–molybdenum cofactor (FeMoco)-catalyzed N2 fixation. Inspired by these biological systems, we report herein our initial investigations into low-coordinate iron hydride chemistry… read more here.
Keywords: chemistry; low coordinate; iron; iron hydride ... See more keywords
Synthesis and characterisation of a very low-coordinate diferrous [2Fe-2S]0 unit.
Sign Up to like & getrecommendations! Published in 2021 at "Chemical communications"
DOI: 10.1039/d1cc04196g
Abstract: Here we present the synthesis of a unique diferrous [2Fe-2S]0 complex with only three-coordinate iron ions via reduction of a four-coordinate diferric [2Fe-2S]2+ complex with concomitant ligand loss. The obtained compounds were thoroughly examined for… read more here.
Keywords: synthesis characterisation; coordinate diferrous; coordinate; characterisation low ... See more keywords