Boosting Nitrate to Ammonia via the Optimization of Key Intermediate Processes by Low‐Coordinated Cu–Cu Sites
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DOI: 10.1002/adfm.202315324
Abstract: The electrochemical reduction of nitrate to ammonia (NO3RR) has emerged as a promising but challenging orientation in sustainable development. Cu is one of the most effective NO3RR catalysts. However, the accumulation of NO2− on their… read more here.
Keywords: low coordinated; nitrate ammonia; ammonia via; coordinated sites ... See more keywords
Unveiling the Role of Low‐Coordinated Sites in CO2 Electroreduction Using Hierarchical Simulation Models
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DOI: 10.1002/cplu.202500223
Abstract: Enhancing efficiency and product selectivity presents a significant challenge in carbon dioxide electroreduction (CO2RR). Recent studies have demonstrated that the solvent in the electrolyte plays a crucial role; however, its specific functions are being investigated… read more here.
Keywords: low coordinated; role; electroreduction; unveiling role ... See more keywords
Low-Coordinated Conductive ZnCu Metal-Organic Frameworks for Highly Selective H2O2 Electrosynthesis.
Sign Up to like & getrecommendations! Published in 2024 at "Small"
DOI: 10.1002/smll.202403808
Abstract: Direct electrosynthesis of hydrogen peroxide (H2O2) with high production rate and high selectivity through the two-electron oxygen reduction reaction (2e-ORR) offers a sustainable alternative to the energy-intensive anthraquinone technology but remains a challenge. Herein, a… read more here.
Keywords: low coordinated; coordinated conductive; electrosynthesis; metal organic ... See more keywords
Low-coordinated Co-Ru dual-atom enables ambient ammoxidation via unlocking competitive adsorption limitations
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DOI: 10.1038/s41467-025-64418-7
Abstract: Direct ammoxidation of biomass-derived alcohols/aldehydes to nitriles faces challenges from N-species competitive adsorption, leading to low efficiency under harsh conditions. Herein, we report the rational design of a single-nitrogen-bridged Co-Ru dual-atom catalyst (CoRu-N-C) on nitrogen-doped… read more here.
Keywords: low coordinated; adsorption; dual atom; competitive adsorption ... See more keywords
Ferrocenyl-substituted low-coordinated heavier group 14 elements.
Sign Up to like & getrecommendations! Published in 2020 at "Dalton transactions"
DOI: 10.1039/d0dt01426e
Abstract: Several examples of stable low-coordinated species of heavier group 14 elements (Si, Ge, Sb, Pb) such as divalent species and multiple-bond compounds have been reported. With the goal in mind to create unprecedented low-coordinated species… read more here.
Keywords: coordinated species; low coordinated; species heavier; group elements ... See more keywords
Electroreduction of CO2 and nitrate for urea synthesis on a low-coordinated copper catalyst.
Sign Up to like & getrecommendations! Published in 2024 at "Chemical communications"
DOI: 10.1039/d4cc05002a
Abstract: Electroreduction of CO2 and NO3- to urea (ECNU) offers a fascinating route for migrating NO3- pollutants and synthesizing valuable urea. Herein, low-coordinated copper (L-Cu) is developed as an effective ECNU catalyst, delivering the highest urea… read more here.
Keywords: low coordinated; electroreduction co2; co2; coordinated copper ... See more keywords
Low-coordinated Co-Mn diatomic sites derived from metal-organic framework nanorod promote electrocatalytic CO2 reduction
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Materials Chemistry A"
DOI: 10.1039/d4ta02261k
Abstract: The manipulation of the geometric coordination structure of diatomic site (DS) catalysts to promote the CO2-to-CO conversion process has garnered significant attention. However, the challenge remains in how to rationally... read more here.
Keywords: low coordinated; coordinated diatomic; derived metal; sites derived ... See more keywords
AuCu bimetallic nanourchins with low-coordinated sites for highly efficient electroreduction of CO2 to acetate at low potential.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc03660g
Abstract: An AuCu bimetallic nanourchin electrocatalyst, rich in low-coordinated Au/Cu atoms, achieves an impressive ∼100% faradaic efficiency (FE) for reduction of CO2 to multicarbon (C2+) products, including 63.8% acetate and 36.2% ethanol at an ultralow potential… read more here.
Keywords: low coordinated; nanourchins low; bimetallic nanourchins; co2 ... See more keywords
Selective urea electrosynthesis from CO2 and NO enabled on low-coordinated Ru1-O3 motifs.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d5cc05848a
Abstract: Electrochemical urea synthesis from CO2 and NO (EUCN) represents an efficient and sustainable approach to convert harmful CO2/NO emissions into high-value urea under ambient conditions. Herein, we design Ru single atoms on amorphous ZnO (Ru1/a-ZnO)… read more here.
Keywords: low coordinated; co2; ru1; ru1 motifs ... See more keywords