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Published in 2023 at "Advanced materials"
DOI: 10.1002/adma.202211260
Abstract: N2 O exhibits unique reactivity in oxidation catalysis, but the high manufacturing costs limit its prospective uses. Direct oxidation of NH3 to N2 O can ameliorate this issue but its implementation is thwarted by suboptimal…
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Keywords:
low valent;
valent manganese;
stabilized ceria;
manganese atoms ... See more keywords
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0
Published in 2020 at "Mendeleev Communications"
DOI: 10.1016/j.mencom.2020.03.025
Abstract: New 10π-electron stabilized O,N-heterocyclic germylene was synthesized and structurally characterized for the first time. Its reduction with potassium in THF resulted in a unique low-valent germanium compound comprising the conjugated Ge4 chain, which was also…
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Keywords:
ge4 chain;
oligogermanium amidophenolate;
valent oligogermanium;
low valent ... See more keywords
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0
Published in 2020 at "Polyhedron"
DOI: 10.1016/j.poly.2020.114420
Abstract: Abstract The dianionic ligand TIPSDAX (2,7-di-tert-butyl-9,9-dimethyl-N4,N5-bis(triisopropylsilyl)-4,5-diamido-9H-xanthene) was synthesized and employed to support low-valent first-row transition metal complexes featuring iron(II) and cobalt(II). These neutral complexes were studied structurally and electrochemically. Cyclic voltammetry revealed a variety of…
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Keywords:
xanthene;
cobalt;
low valent;
ligand ... See more keywords
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0
Published in 2021 at "Polyhedron"
DOI: 10.1016/j.poly.2021.115228
Abstract: Abstract The photogeneration of X2 is the key to achieving an efficient HX-splitting photocycle, as it is more thermodynamically and kinetically challenging than its H2 half reaction counterpart. Here we report a strategy that enables…
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Keywords:
chemistry;
photohalogen elimination;
low valent;
valent binuclear ... See more keywords
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0
Published in 2020 at "Tetrahedron"
DOI: 10.1016/j.tet.2020.131725
Abstract: ABSTRACT The reductive intermolecular coupling of phthalimides with esters by low-valent titanium gave five-, six-, and seven-membered cyclized products as α-hydroxyketones and their further reduced ketones. The obtained cyclized products were transformed to alkylideneisoindolin-1-ones. The…
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Keywords:
phthalimides esters;
low valent;
coupling phthalimides;
valent titanium ... See more keywords
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2
Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00763
Abstract: ConspectusSilylenes are divalent silicon species with an unoccupied 3p orbital and one lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato-based silylenes, which stems from the intramolecular imino-N…
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Keywords:
group;
bis nhsi;
main group;
low valent ... See more keywords
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Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.0c02820
Abstract: A 4-center, 6π-conjugated, multiply bonded trigonal-planar complex, [Sb{Cr(CO)5}3]- (1), was synthesized via the hydride abstraction of [HSb{Cr(CO)5}3]2- (1-H) with HBF4·H2O, with the release of high yields of H2. The oxidation state of the Sb atom…
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Keywords:
planar complex;
low valent;
trigonal planar;
multiply bonded ... See more keywords
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2
Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.6b02616
Abstract: Mechanistic studies of the reduction of FeIII and FeII salts by aryl Grignard reagents in toluene/tetrahydrofuran mixtures in the absence of a supporting ligand, as well as structural insights regarding the nature of the low-valent…
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Keywords:
reduction;
grignard reagents;
low valent;
salts aryl ... See more keywords
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0
Published in 2021 at "Organometallics"
DOI: 10.1021/acs.organomet.0c00738
Abstract: Reactivity of low-valent AlII species containing redox-active dpp-dad or dpp-Bian ligand (La = dpp-dad = [(2,6-iPr2C6H3)NC(CH3)]2; Lb = dpp-Bian = 1,2-[(2,6-iPr2C6H3)NC]2C10H6) toward nitrogen-rich...
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Keywords:
dpp;
nitrogen rich;
low valent;
redox active ... See more keywords
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Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00319
Abstract: We demonstrate a simple and generalizable method for the one pot, in situ formation of bimetallic metal–organic framework (MOF) materials decorated with crystallographically defined, low-valent metal sites. Solvothermal reactions between poly(carboxylated) aryl(phosphine) ligands and mixtures…
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Keywords:
metal;
low valent;
valent metal;
one pot ... See more keywords
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1
Published in 2022 at "Organic letters"
DOI: 10.1021/acs.orglett.2c04090
Abstract: Herein, we have developed an efficient tungsten-catalyzed homogeneous system for oxidative dehydrogenative coupling of anilines to selectively produce various azoaromatics and azoxyaromatics as well as 2-substituted indolone N-oxides by simply regulating the reaction solvent with…
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Keywords:
oxidative dehydrogenative;
low valent;
coupling anilines;
valent tungsten ... See more keywords