Photochemical C–C Bond Formation in Luminescent Zirconium Complexes with CNN Pincer Ligands
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DOI: 10.1021/acs.organomet.8b00388
Abstract: The complexes Zr(HCNN)2 and Zr(MeCNN)2 were prepared via reaction of the ligand precursors 2-phenyl-6-(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine, H2HCNN, and 2-(3,5-dimethyl-phenyl)-6-(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine, H2MeCNN, with tetrabenzyl zirconium. Both complexes are photoluminescent upon excitation with visible light and exhibit remarkably long emission… read more here.
Keywords: zirconium complexes; bond formation; luminescent zirconium; formation luminescent ... See more keywords