A Luminescent Zirconium-Pentacarboxylate Framework with 10-Connected Zr6 Clusters for Dichromate Detection.
Sign Up to like & getrecommendations! Published in 2025 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.5c02368
Abstract: Zirconium-based metal-organic frameworks (Zr-MOFs) have received great attention due to their abundant structural diversity and controllable functionalizations. However, pentacarboxylic acid-based Zr-MOFs are less studied. Herein, we report a new pentacarboxylic acid-based organic linker, 4″,4‴″,4‴‴″-((4-(4,5-bis(4-carboxyphenyl)-1H-imidazol-2-yl)phenyl)methanetriyl)tris(([1,1':4',1″-terphenyl]-4-carboxylic acid)),… read more here.
Keywords: zirconium; dichromate detection; zirconium pentacarboxylate; hiam 4055 ... See more keywords
Photochemical C–C Bond Formation in Luminescent Zirconium Complexes with CNN Pincer Ligands
Sign Up to like & getrecommendations! Published in 2018 at "Organometallics"
DOI: 10.1021/acs.organomet.8b00388
Abstract: The complexes Zr(HCNN)2 and Zr(MeCNN)2 were prepared via reaction of the ligand precursors 2-phenyl-6-(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine, H2HCNN, and 2-(3,5-dimethyl-phenyl)-6-(5-methyl-3-phenyl-1H-pyrrol-2-yl)pyridine, H2MeCNN, with tetrabenzyl zirconium. Both complexes are photoluminescent upon excitation with visible light and exhibit remarkably long emission… read more here.
Keywords: zirconium complexes; bond formation; luminescent zirconium; formation luminescent ... See more keywords