Porphyriynes: 18-π-Conjugated Macrocycles Incorporating a Triple Bond.
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DOI: 10.1021/acs.orglett.2c00356
Abstract: Tetraphenylporphyriyne (Pyne1), a novel porphyrin analogue with a C≡C bond incorporated into an 18-π-conjugated system, has been created via cleavage of the N-confused pyrrolic ring in Ag(III) N-confused tetraphenylporphyrin. The structure of Pyne1 was confirmed… read more here.
Keywords: conjugated macrocycles; incorporating triple; macrocycles incorporating; porphyriynes conjugated ... See more keywords