Articles with "macrocyclic compounds" as a keyword



How does the ligands structure surrounding metal-N4 of Co-based macrocyclic compounds affect electrochemical reduction of CO2 performance?

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Published in 2020 at "Electrochimica Acta"

DOI: 10.1016/j.electacta.2019.135283

Abstract: Abstract Metal-Nx-C based materials have emerged as one of the most promising electrocatalysts for electrochemical reduction of carbon dioxide (ERCD). Co-based macrocyclic compounds have shown unique performance, however, of which the relationship between the ligands… read more here.

Keywords: macrocyclic compounds; based macrocyclic; metal based; structure ... See more keywords

Synthesis of silicon-containing macrocyclic compounds by using intramolecular [2+2] photocycloaddition reactions of bis-dimethylsilyl-linked styrenes and stilbenes

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Published in 2018 at "Journal of Photochemistry and Photobiology A: Chemistry"

DOI: 10.1016/j.jphotochem.2018.06.038

Abstract: Abstract A method for the synthesis of silicon-containing macrocyclic compounds, using intramolecular [2 + 2] photocycloaddition reactions of bis-dimethylsilyl-linked styrene or stilbene derivatives, is described. Photoirradiation of benzene solutions of o- and m-bis(dimethylsilylmethyl)benzene derivatives, containing two styrene… read more here.

Keywords: macrocyclic compounds; synthesis silicon; compounds using; silicon containing ... See more keywords

Quantification of Intracellular Accumulation and Retention of Lysosomotropic Macrocyclic Compounds by High-Throughput Imaging of Lysosomal Changes.

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Published in 2019 at "Journal of pharmaceutical sciences"

DOI: 10.1016/j.xphs.2018.11.001

Abstract: Many marketed pharmaceuticals reach extremely high tissue concentrations due to accumulation in lysosomes (lysosomotropism). Quantitative prediction of intracellular concentrations of accumulating drugs is challenging, especially for macrocyclic compounds that mainly do not fit in current… read more here.

Keywords: macrocyclic compounds; intracellular accumulation; accumulation; throughput imaging ... See more keywords

Validating Small-Molecule Force Fields for Macrocyclic Compounds Using NMR Data in Different Solvents

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Published in 2024 at "Journal of Chemical Information and Modeling"

DOI: 10.1021/acs.jcim.4c01120

Abstract: Macrocycles are a promising class of compounds as therapeutics for difficult drug targets due to a favorable combination of properties: They often exhibit improved binding affinity compared to their linear counterparts due to their reduced… read more here.

Keywords: force fields; force; molecule force; macrocyclic compounds ... See more keywords

Supramolecular Organocatalysis in Water Mediated by Macrocyclic Compounds

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Published in 2018 at "Frontiers in Chemistry"

DOI: 10.3389/fchem.2018.00084

Abstract: In the last decades many efforts have been devoted to design supramolecular organocatalysts able to work in water as the reaction medium. The use of water as solvent provides promising benefits with respect to environmental… read more here.

Keywords: macrocyclic compounds; organocatalysis water; water; reaction ... See more keywords

Macrocyclic Compounds: Metal Oxide Particles Nanocomposite Thin Films Deposited by MAPLE

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Published in 2023 at "Materials"

DOI: 10.3390/ma16062480

Abstract: Nanocomposite films based on macrocyclic compounds (zinc phthalocyanine (ZnPc) and 5,10,15,20-tetra(4-pyridyl) 21H,23H-porphyrin (TPyP)) and metal oxide nanoparticles (ZnO or CuO) were deposited by matrix-assisted pulsed laser evaporation (MAPLE). 1,4-dioxane was used as a solvent in… read more here.

Keywords: maple; deposited maple; metal oxide; films deposited ... See more keywords