Macrocyclic enforcement of twist in a secondary amide: reactivity and influence on photoisomerisation.
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DOI: 10.1039/d2cc04780b
Abstract: We report a penta-azamacrocycle (cDP2) containing a twisted secondary amide residue with a twist angle (τ) of 28° and pyramidalization parameter (χN) of 53°. Consequently, cDP2 is reactive towards a host of nucleophiles such as… read more here.
Keywords: twist secondary; enforcement twist; macrocyclic enforcement; twist ... See more keywords