Articles with "macrocyclic tetranuclear" as a keyword



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A macrocyclic tetranuclear ZnII complex as a receptor for selective dual fluorescence sensing of F− and AcO−: effect of a macrocyclic ligand

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Published in 2019 at "New Journal of Chemistry"

DOI: 10.1039/c9nj03481a

Abstract: Fluorimetric detection of F−/AcO− with an additional ‘INHIBIT’ logic gate response for F−/H+ and AcO−/H+ in an aqueous-methanol medium by a 48-membered macrocyclic ZnII-complex DAS has been explored by combined experimental and theoretical study. read more here.

Keywords: complex receptor; znii; macrocyclic tetranuclear; receptor selective ... See more keywords
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Macrocyclic tetranuclear double-butterfly Fe/S carbonyl clusters as [FeFe]-hydrogenase models

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Published in 2020 at "Supramolecular Chemistry"

DOI: 10.1080/10610278.2020.1837828

Abstract: ABSTRACT Cyclic bis(diironhexacarbonyl) dithiolates with double-butterfly architecture and centrosymmetricity are supramolecular coordination complexes that mimic the structure and function of the diiron unit in the H-cluster of [FeFe]-hydrogenase. These ferracycles are an important and interesting… read more here.

Keywords: fefe hydrogenase; macrocyclic tetranuclear; double butterfly; hydrogenase ... See more keywords