Macrolactam Synthesis via Ring-Closing Alkene-Alkene Cross-Coupling Reactions.
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DOI: 10.1021/acs.orglett.0c03801
Abstract: Reported herein is a practical method for macrolactam synthesis via a Rh(III)-catalyzed ring closing alkene-alkene cross-coupling reaction. The reaction proceeded via a Rh-catalyzed alkenyl sp2 C-H activation process, which allows access to macrocyclic molecules of… read more here.
Keywords: alkene alkene; macrolactam synthesis; closing alkene; synthesis via ... See more keywords