Macromolecular architectures through organocatalysis
Sign Up to like & getrecommendations! Published in 2017 at "Progress in Polymer Science"
DOI: 10.1016/j.progpolymsci.2017.07.002
Abstract: Abstract In virtue of the rising demand for metal-free polymeric materials, organocatalytic polymerization has emerged and blossomed unprecedentedly in the past 15 years into an appealing research area and a powerful arsenal for polymer synthesis.… read more here.
Keywords: macromolecular architectures; polymer; architectures organocatalysis;
C1 polymerization: a unique tool towards polyethylene-based complex macromolecular architectures
Sign Up to like & getrecommendations! Published in 2017 at "Polymer Chemistry"
DOI: 10.1039/c7py00581d
Abstract: The recent developments in organoborane initiated C1 polymerization (chain grows by one atom at a time) of ylides open unique horizons towards well-defined/perfectly linear polymethylenes (equivalent to polyethylenes, PE) and PE-based complex macromolecular architectures. The… read more here.
Keywords: polymerization; based complex; unique tool; macromolecular architectures ... See more keywords
Coarsening Kinetics of Complex Macromolecular Architectures in Bad Solvent
Sign Up to like & getrecommendations! Published in 2020 at "Polymers"
DOI: 10.3390/polym12030531
Abstract: This study reports a general scenario for the out-of-equilibrium features of collapsing polymeric architectures. We use molecular dynamics simulations to characterize the coarsening kinetics, in bad solvent, for several macromolecular systems with an increasing degree… read more here.
Keywords: kinetics complex; macromolecular architectures; architectures bad; complex macromolecular ... See more keywords
Recent Advances in the Synthesis of Complex Macromolecular Architectures Based on Poly(N-vinyl pyrrolidone) and the RAFT Polymerization Technique
Sign Up to like & getrecommendations! Published in 2022 at "Polymers"
DOI: 10.3390/polym14040701
Abstract: Recent advances in the controlled RAFT polymerization of complex macromolecular architectures based on poly(N-vinyl pyrrolidone), PNVP, are summarized in this review article. Special interest is given to the synthesis of statistical copolymers, block copolymers, and… read more here.
Keywords: complex macromolecular; macromolecular architectures; raft; raft polymerization ... See more keywords
Precise Synthesis of Macromolecular Architectures by Novel Iterative Methodology Combining Living Anionic Polymerization with Specially Designed Linking Chemistry
Sign Up to like & getrecommendations! Published in 2017 at "Polymers"
DOI: 10.3390/polym9100470
Abstract: This article reviews the development of a novel all-around iterative methodology combining living anionic polymerization with specially designed linking chemistry for macromolecular architecture syntheses. The methodology is designed in such a way that the same… read more here.
Keywords: methodology; macromolecular architectures; chemistry; methodology combining ... See more keywords