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Published in 2025 at "Advanced Functional Materials"
DOI: 10.1002/adfm.202523943
Abstract: A mechanistic pathway is presented for the evolution of CdSe and CdTeSe magic‐size clusters (MSCs) in dispersion of CdTe MSC‐371 (displaying optical absorption peaking at ≈371 nm), MSC‐417, and/or MSC‐448 at room temperature. Synthesized with a…
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Keywords:
cdtese magic;
cdse cdtese;
magic size;
room temperature ... See more keywords
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Published in 2019 at "Nano Research"
DOI: 10.1007/s12274-019-2386-8
Abstract: We report, for the first time, the synthesis of CdS magic-size clusters (MSCs) which exhibit a single sharp absorption peaking at ∼ 361 nm, along with sharp band edge photoemission at ∼ 377 nm and…
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Keywords:
absorption;
size clusters;
cds magic;
magic size ... See more keywords
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Published in 2022 at "ACS applied materials & interfaces"
DOI: 10.1021/acsami.1c20953
Abstract: All-inorganic metal nanocrystals (NCs) offer an ideal platform for atomically precise surface design and show improved electrocatalytic activity compared to conventional NCs capped with organic ligands. Here, we show the possibility of obtaining colloidal all-inorganic…
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Keywords:
inorganic metal;
magic size;
inorganic ncs;
colloidal inorganic ... See more keywords
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Published in 2023 at "ACS Central Science"
DOI: 10.1021/acscentsci.2c01394
Abstract: The field of isomerization reactions for colloidal semiconductor magic-size clusters (MSCs) remains largely unexplored. Here, we show that MSCs isomerize via two fundamental pathways that are regulated by the acidity and amount of an incoming…
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Keywords:
room temperature;
isomerization;
magic size;
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Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.3c12853
Abstract: Ion exchange is an effective postsynthesis strategy for the design of colloidal nanomaterials with unique structures and properties. In contrast to the rapid development of cation exchange (CE), the study of anion exchange is still…
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Keywords:
reaction;
anion exchange;
exchange;
magic size ... See more keywords
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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c16188
Abstract: Facile synthesis of atomically precise semiconductor nanoclusters remains an important challenge, especially for those with heavier chalcogens. Combining coordination and colloidal methods, we developed a simple approach for synthesizing an atomically precise CdTe nanocluster with…
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Keywords:
facile synthesis;
semiconductor;
size atomic;
magic size ... See more keywords
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Published in 2025 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.5c02549
Abstract: Despite the symmetric, achiral atomic lattices typically found in binary semiconductor nanocrystals, we show that during their early formation stages, especially in the magic-size cluster (MSC) regime, chirality can be present in these metastable, transient…
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Keywords:
enantiomerically biased;
cluster;
magic size;
chiral cds ... See more keywords
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Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt03418b
Abstract: The synthesis of atomically precise semiconductors Ag-S clusters is a subject of intense research interest, yet the formation mechanism of such nanoclusters remains obscure due to their uncontrolled fast nucleation process in solution. Herein, we…
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Keywords:
nucleation;
ph3p;
magic size;
cluster nucleation ... See more keywords