Bimetallic Bis-anion Cascade Complexes of Magnesium in Nonaqueous Solution.
Sign Up to like & getrecommendations! Published in 2020 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b03710
Abstract: Bimetallic magnesium(II) complexes are gaining significant interest in catalysis, yet their fundamental formation and behavior in organic media remain surprisingly unexplored relative to other divalent cations. To understand key principles of their formation, we investigate… read more here.
Keywords: anion; cascade complexes; bimetallic magnesium; magnesium ... See more keywords
Zinc and Magnesium Complexes Bearing Oxazoline-Derived Ligands and Their Application for Ring Opening Polymerization of Cyclic Esters
Sign Up to like & getrecommendations! Published in 2018 at "ACS Omega"
DOI: 10.1021/acsomega.8b01997
Abstract: A family of different substituents aza(oxazoline) ligand-based zinc and magnesium complexes were synthesized. These complexes can catalyze ring opening polymerization of ε-caprolactone (ε-CL) and lactide (LA) to produce poly-ε-caprolactone and polylactide with good conversions. Polymerization… read more here.
Keywords: ring opening; polymerization; zinc magnesium; magnesium ... See more keywords
Lithium and magnesium complexes by using pyridyl-pendanted unsymmetrical β-diketiminates: syntheses and application as catalysts for the hydroboration of carbonyl compounds.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d1dt03235f
Abstract: The push for environmentally benign and sustainable chemical processes has reinforced the demand to displace transition metals with cheap, nontoxic and naturally abundant metals. To fulfil this requirement, we endeavored to synthesize alkali- and alkaline… read more here.
Keywords: magnesium; pyridyl pendanted; unsymmetrical diketiminates; magnesium complexes ... See more keywords
Luminescent magnesium complexes with intra- and inter-ligand charge transfer.
Sign Up to like & getrecommendations! Published in 2022 at "Chemical communications"
DOI: 10.1039/d2cc04142a
Abstract: Herein, we report two 2,2'-pyridylpyrrolide (PyPyrH) ligand supported magnesium complexes (1 and 2), which demonstrate bright luminescence with a quantum yield of 22% and 14% in the solid state, respectively. Theoretical calculations reveal that their… read more here.
Keywords: inter ligand; ligand; magnesium complexes; ligand charge ... See more keywords
Structural Investigation of Magnesium Complexes Supported by a Thiopyridyl Scorpionate Ligand
Sign Up to like & getrecommendations! Published in 2022 at "Molecules"
DOI: 10.3390/molecules27144564
Abstract: Herein, we report the synthesis of a series of heteroleptic magnesium complexes stabilized with the scorpionate ligand tris(2-pyridylthio)methanide (Tptm). The compounds of the general formula [Mg(Tptm)(X)] (1-X; X = Cl, Br, I) were obtained via… read more here.
Keywords: investigation magnesium; scorpionate ligand; ligand; magnesium complexes ... See more keywords
Magnesium Phthalocyanines and Tetrapyrazinoporphyrazines: The Influence of a Solvent and a Delivery System on a Dissociation of Central Metal in Acidic Media
Sign Up to like & getrecommendations! Published in 2022 at "Pharmaceuticals"
DOI: 10.3390/ph15040409
Abstract: Magnesium complexes of phthalocyanines (Pcs) and their aza-analogues have a great potential in medical applications or fluorescence detection. They are known to demetallate to metal-free ligands in acidic environments, however, detailed investigation of this process… read more here.
Keywords: metal; magnesium complexes; metal free; delivery system ... See more keywords