Hydrodeoxygenation of isocyanates: snapshots of a magnesium-mediated C[double bond, length as m-dash]O bond cleavage.
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DOI: 10.1039/c7sc00117g
Abstract: Organic isocyanates are readily converted to methyl amine products through their hydroboration with HBpin in the presence of a β-diketiminato magnesium catalyst. Although borylated amide and N-,O-bis(boryl)hemiaminal species have been identified as intermediates during the… read more here.
Keywords: bond; snapshots magnesium; magnesium; isocyanates snapshots ... See more keywords
Magnesium-mediated arylation of amines via C-F bond activation of fluoroarenes.
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DOI: 10.1039/c9cc01670h
Abstract: A series of new Mg(ii) amides featuring a bulky β-diketiminate backstop ligand, has been synthesised. These complexes are demonstrated to be excellent sources of nucleophilic amides that can participate in rapid C-F activation of several… read more here.
Keywords: arylation amines; amines via; mediated arylation; activation ... See more keywords
Auxin Is Involved in Magnesium-Mediated Photoprotection in Photosystems of Alfalfa Seedlings Under Aluminum Stress
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DOI: 10.3389/fpls.2020.00746
Abstract: The objective of this study was to investigate the effects of Mg and IAA on the photosystems of Al-stressed alfalfa (Medicago sativa L.). Alfalfa seedlings with or without apical buds were exposed to solutions fully… read more here.
Keywords: alfalfa seedlings; auxin involved; apical buds; involved magnesium ... See more keywords