Organomagnesia: Reversibly High Carbon Dioxide Uptake by Magnesium Pyrazolates
Sign Up to like & getrecommendations! Published in 2024 at "Advanced Science"
DOI: 10.1002/advs.202403295
Abstract: A series of new pyrazolate and mixed pyrazolate/pyrazole magnesium complexes is described and their reactivity toward carbon dioxide is examined. The dimeric complex [Mg(pztBu,tBu)2]2 inserts CO2 instantly and quantitatively forming the tetrameric complex [Mg(CO2·pztBu,tBu)2]4 and… read more here.
Keywords: carbon dioxide; tbu; magnesium pyrazolates;