Effect of Structure on the Spin Switching and Magnetic Bistability of Solid-State Aryl Dicyanomethyl Monoradicals and Diradicals
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DOI: 10.1021/acsomega.9b01658
Abstract: Stable organic radicals with switchable spin states have applications in medicine, biology, and material science. An emerging class of such spin-switchable radicals is based on dicyanomethyl radicals, which are typically thermally and air-stable species that… read more here.
Keywords: state; solid state; spin switching; structure ... See more keywords
Magnetic Bistability in Naphtho-1,3,2-dithiazolyl: Solid State Interconversion of a Thiazyl π-Radical and Its N-N σ-Bonded Dimer.
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DOI: 10.1021/jacs.7b13699
Abstract: Crystals of the heterocyclic radical naphtho-1,3,2-dithiazolyl NDTA display magnetic bistability with a well-defined hysteretic phase transition at Tc↓ = 128(2) K and Tc↑ = 188(2) K. The magnetic signature arises from a radical/dimer interconversion involving… read more here.
Keywords: interconversion; magnetic bistability; bistability; naphtho dithiazolyl ... See more keywords