Structure and bonding of proximity‐enforced main‐group dimers stabilized by a rigid naphthyridine diimine ligand
Sign Up to like & getrecommendations! Published in 2022 at "Journal of Computational Chemistry"
DOI: 10.1002/jcc.26994
Abstract: The development of ligands capable of effectively stabilizing highly reactive main‐group species has led to the experimental realization of a variety of systems with fascinating properties. In this work, we computationally investigate the electronic, structural,… read more here.
Keywords: stabilized rigid; main group; chemistry; proximity enforced ... See more keywords
The Results of the Combine Treatment of Patients with Liver Bilobar Metastases from Colorectal Cancer Using Radiofrequency Ablation
Sign Up to like & getrecommendations! Published in 2018 at "Indian Journal of Surgical Oncology"
DOI: 10.1007/s13193-018-0740-z
Abstract: Colorectal cancer (CRC) is the third most common cancer worldwide. The mortality from CRC remains very high. The main cause of such a high mortality is a disseminate process with the appearance of distant metastases.… read more here.
Keywords: treatment; colorectal cancer; group; main group ... See more keywords
Main group metal chalcogenidometalates with transition metal complexes of 1,10-phenanthroline and 2,2′-bipyridine
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2016.08.009
Abstract: Abstract Inorganic-organic hybrid main group metal chalcogenidometalates have attracted considerable interest due to their various topological structures and potential applications in solid electrolytes, non-oxygen zeolites, and photo- or electro-catalysts. These compounds are typically synthesized under… read more here.
Keywords: group metal; main group; metal; metal chalcogenidometalates ... See more keywords
Dative bonding in main group compounds
Sign Up to like & getrecommendations! Published in 2017 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2017.03.026
Abstract: Abstract The progress in experimental and theoretical research in the area of main group compounds that possess dative bonds, which was made in the last decade, is summarized. The focus lies on the information about… read more here.
Keywords: dative bonding; bonding main; chemistry; main group ... See more keywords
Investigation and determination of acrylamide in the main group of cereal products using advanced microextraction method coupled with gas chromatography-mass spectrometry
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Cereal Science"
DOI: 10.1016/j.jcs.2019.03.019
Abstract: Abstract Cereal products as the main group of food diet have most important effect on human health. Acrylamide as a dangerous toxic compound has highly potential to be form in carbohydrates and proteins-rich foods at… read more here.
Keywords: main group; cereal products; cereal; group cereal ... See more keywords
Luminescent molecules of main group elements: Recent advances on synthesis, properties and their application on fluorescent bioimaging (FBI) ☆
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2017.11.042
Abstract: Abstract The Environment-related parameters, including pH, oxygen level and viscosity play pivotal functions in controlling the physical, chemical and biological performance of local molecules. Irregular modification in these features would cause cellular malfunction can indicate… read more here.
Keywords: main group; luminescent molecules; level; oxygen level ... See more keywords
Mixed main group transition metal clusters: Reactions of [Ru 3 (CO) 10 (μ-dppm)] with Ph 3 SnH
Sign Up to like & getrecommendations! Published in 2017 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2017.03.052
Abstract: Abstract Novel dppm-ligated ruthenium-tin clusters have been prepared from the reaction of [Ru3(CO)10(μ-dppm)] with Ph3SnH. At room temperature and in the presence of Me3NO, [Ru3(CO)9(SnPh3) (μ-dppm) (μ-H)] (1) is produced from the formal loss of… read more here.
Keywords: ruthenium; ru3 snph3; dppm; main group ... See more keywords
Unique Phosphorus-Based Avenues for the Tuning of Functional Materials.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00707
Abstract: ConspectusRecent ground-breaking advances in synthetic chemistry have transformed main-group molecules from simple laboratory curiosities into powerful materials for a range of applications in all realms of life. Electron-accepting or -deficient materials, in particular, have been… read more here.
Keywords: phosphorus based; chemistry; main group; electron ... See more keywords
Chelating Bis-silylenes As Powerful Ligands To Enable Unusual Low-Valent Main-Group Element Functions.
Sign Up to like & getrecommendations! Published in 2023 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.2c00763
Abstract: ConspectusSilylenes are divalent silicon species with an unoccupied 3p orbital and one lone pair of electrons at the SiII center. Owing to the excellent σ-donating ability of amidinato-based silylenes, which stems from the intramolecular imino-N… read more here.
Keywords: group; bis nhsi; main group; low valent ... See more keywords
Pushing Chemical Boundaries with N-Heterocyclic Olefins (NHOs): From Catalysis to Main Group Element Chemistry.
Sign Up to like & getrecommendations! Published in 2017 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.7b00264
Abstract: N-Heterocyclic olefins (NHOs) have gone from the topic of a few scattered (but important) reports in the early 1990s to very recently being a ligand/reagent of choice in the far-reaching research fields of organocatalysis, olefin… read more here.
Keywords: group element; chemistry; main group; group ... See more keywords
Oxidative Addition and Reductive Elimination at Main-Group Element Centers.
Sign Up to like & getrecommendations! Published in 2018 at "Chemical reviews"
DOI: 10.1021/acs.chemrev.7b00572
Abstract: Oxidative addition and reductive elimination are key steps in a wide variety of catalytic reactions mediated by transition-metal complexes. Historically, this reactivity has been considered to be the exclusive domain of d-block elements. However, this… read more here.
Keywords: oxidative addition; reductive elimination; main group; group ... See more keywords