Effective synthesis of fluorine-containing phenanthrene bearing hydroxyl group using Mallory reaction and its application for fluorinated polyesters
Sign Up to like & getrecommendations! Published in 2019 at "Journal of Fluorine Chemistry"
DOI: 10.1016/j.jfluchem.2018.11.017
Abstract: Abstract Mallory reaction of 1,2-bis(4-hydroxyphenyl)-3,3,4,4,5,5-hexafluorocyclopentene under light irradiation (λ = 356 nm) in the presence of iodine as an oxidant proceeded to give fluorine-containing phenanthrene bearing hydroxyl groups, 6,9-bis(4-hydroxyphenyl)-1,1,2,2,3,3-hexafluoro-2,3-dihydro-1H-cyclopenta[l]phenanthrene. Polycondensation of the prepared fluorine-containing phenanthrene with various acid… read more here.
Keywords: type polyesters; mallory reaction; containing phenanthrene; fluorine containing ... See more keywords
Synthesis of azahelicenes through Mallory reaction of imine precursors: corannulene substrates provide an exception to the rule in oxidative photocyclizations of diarylethenes†
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DOI: 10.1039/d0sc06730j
Abstract: Typically, the synthesis of phenanthrene-based polycyclic aromatic hydrocarbons relies on the Mallory reaction. In this approach, stilbene (PhCH Created by potrace 1.16, written by Peter Selinger 2001-2019 CHPh)-based precursors undergo an oxidative photocyclization reaction to… read more here.
Keywords: synthesis azahelicenes; 320 320; imine precursors; mallory reaction ... See more keywords