Electro and photoreduction of CO2 driven by manganese-carbonyl molecular catalysts
Sign Up to like & getrecommendations! Published in 2018 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2018.01.014
Abstract: Abstract Manganese carbonyl complexes have become popular homogeneous catalysts for carbon dioxide electro- or photoreduction since the beginning of the 2010s. This article presents a comprehensive survey of all the Mn carbonyl systems reported during… read more here.
Keywords: electro photoreduction; photoreduction co2; photoreduction; manganese carbonyl ... See more keywords
Manganese Carbonyl Complexes as Selective Electrocatalysts for CO2 Reduction in Water and Organic Solvents
Sign Up to like & getrecommendations! Published in 2022 at "Accounts of Chemical Research"
DOI: 10.1021/acs.accounts.1c00692
Abstract: Conspectus The electrochemical reduction of CO2 provides a way to sustainably generate carbon-based fuels and feedstocks. Molecular CO2 reduction electrocatalysts provide tunable reaction centers offering an approach to control the selectivity of catalysis. Manganese carbonyl… read more here.
Keywords: reduction; co2 reduction; water; manganese carbonyl ... See more keywords
Manganese Carbonyl Compounds Reveal Ultrafast Metal–Solvent Interactions
Sign Up to like & getrecommendations! Published in 2019 at "Organometallics"
DOI: 10.1021/acs.organomet.9b00212
Abstract: Herein, we exemplify that time-resolved multiple-probe spectroscopy (TRMPS) with infrared detection can be used to observe and quantify the dynamic processes occurring during the solvation of a catalytically competent manganese(I) carbonyl compound. TRMPS has been… read more here.
Keywords: reveal ultrafast; ultrafast metal; carbonyl compounds; metal ... See more keywords
Inter-ligand intramolecular through-space anisotropic shielding in a series of manganese carbonyl phosphorous compounds.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c9dt03100f
Abstract: Eight novel manganese carbonyl complexes of the type [Mn(bpy-tBu)(CO)3PR3]+ (bpy-tBu = 4,4'-di-tert-butyl-2,2'-bipyridine; R = Cy, nBu, Me, p-tol, Ph, p-F-Ph, OEt, and OMe), have been synthesized and characterized by 1H NMR, FTIR, UV/Vis, HRMS and… read more here.
Keywords: inter ligand; anisotropic shielding; bpy tbu; series ... See more keywords
Coupling of fluoroborylene ligands in manganese carbonyl chemistry to give a difluorodiborene ligand
Sign Up to like & getrecommendations! Published in 2019 at "New Journal of Chemistry"
DOI: 10.1039/c9nj01209e
Abstract: A bridging difluorodiborene μ-B2F2 ligand has been observed in two of the three lowest energy Mn2(BF)2(CO)7 structures as well as in the lowest energy Mn2(BF)2(CO)6 structure. read more here.
Keywords: difluorodiborene; coupling fluoroborylene; fluoroborylene ligands; manganese carbonyl ... See more keywords
Manganese carbonyl induced cationic reversible addition–fragmentation chain transfer (C-RAFT) polymerization under visible light
Sign Up to like & getrecommendations! Published in 2020 at "Polymer Chemistry"
DOI: 10.1039/c9py01785b
Abstract: The manganese carbonyl induced cationic reversible addition–fragmentation chain transfer (C-RAFT) polymerization under mild conditions such as visible light, room temperature and even in the presence of small quantities of water is reported. In this method,… read more here.
Keywords: polymerization; raft; vinyl ether; poly ... See more keywords