Magnetic Properties of bis-o-Benzosemiquinonato Cobalt(II), Iron(II), and Manganese(II) Complexes with 2,2'-Biquinoline and 1,4-Di-tert-Butyl-1,4-Diazabutadiene
Sign Up to like & getrecommendations! Published in 2020 at "Theoretical and Experimental Chemistry"
DOI: 10.1007/s11237-020-09663-1
Abstract: New heteroligand cobalt(II), iron(II), and manganese(II) complexes of the M(3,6-SQ)2L type bearing 3,6-di-tert-butyl-o-benzosemiquinonato ligands (3,6-SQ) and 2,2'-biquinoline or 1,4-di-tert-butyl-1,4-diazabutadiene-1,3 as neutral ligands (L) have been synthesized and characterized. It was shown on the basis of… read more here.
Keywords: cobalt iron; tert butyl; manganese complexes;
Recent advances in the catalytic oxidation of alkene and alkane substrates using immobilized manganese complexes with nitrogen containing ligands
Sign Up to like & getrecommendations! Published in 2019 at "Coordination Chemistry Reviews"
DOI: 10.1016/j.ccr.2018.12.004
Abstract: Abstract In recent years, many supported manganese catalysts for the oxidative transformations of hydrocarbons by various terminal oxidants have been designed and tested. A vast range of inorganic (e.g. silica, carbon, zeolites), organic (e.g. polymers,… read more here.
Keywords: manganese complexes; catalytic oxidation; containing ligands; recent advances ... See more keywords
Electrochemical study of the Mn(II/III) oxidation of tris(polypyridine)manganese(II) complexes
Sign Up to like & getrecommendations! Published in 2021 at "Electrochimica Acta"
DOI: 10.1016/j.electacta.2021.138965
Abstract: Abstract The electrochemical behaviour of a series of tris(polypyridine)manganese(II) complexes containing substituents ranging from electron withdrawing (Cl) to electron donating (OMe) is presented. The Mn(II/III) redox couple shows irreversible behaviour with large peak potential separations… read more here.
Keywords: manganese complexes; oxidation; study; electrochemical study ... See more keywords
In vitro and in silico study of the biological activity of manganese(III) inverse-[9-MC-3]-metallacrowns and manganese(II) complexes with the anti-inflammatory drugs diclofenac or indomethacin.
Sign Up to like & getrecommendations! Published in 2018 at "Journal of inorganic biochemistry"
DOI: 10.1016/j.jinorgbio.2018.07.007
Abstract: In the present contribution, the biological properties of four manganese complexes with the non-steroidal anti-inflammatory drugs sodium diclofenac (Nadicl) or indomethacin (Hindo) in the presence or absence of salicylaldoxime (Η2sao), i.e. [Μn6(O)2(dicl)2(sao)6(CH3OH)6] 1, [Μn6(O)2(indo)2(sao)6(H2O)4], 2,… read more here.
Keywords: anti inflammatory; biological activity; vitro silico; manganese complexes ... See more keywords
The Full d3-d5 Redox Series of Mononuclear Manganese Complexes: Geometries and Electronic Structures of [Mn(dgpy)2]n.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01680
Abstract: Although manganese ions exhibit a rich redox chemistry, redox processes are often accompanied by structural reorganization and a high propensity for ligand substitution, so that no complete structurally characterized manganese(II,III,IV) complex series without significant ligand… read more here.
Keywords: series; manganese iii; chemistry; dgpy ... See more keywords
Synthesis, Characterization, and Thermal Properties of N-alkyl β-Diketiminate Manganese Complexes.
Sign Up to like & getrecommendations! Published in 2018 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b02476
Abstract: A series of N, N'-dialkyl-β-diketiminato manganese(II) complexes was synthesized and characterized by single crystal X-ray diffraction, UV-vis and FTIR spectroscopy, and then assayed for volatility, thermal stability, and surface reactivity relevant to vapor-phase film growth… read more here.
Keywords: reactivity; thermal properties; manganese complexes; characterization thermal ... See more keywords
Gas-Phase Characterization of Redox-Active Manganese Complexes.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Society for Mass Spectrometry"
DOI: 10.1021/jasms.4c00113
Abstract: Manganese complexes exhibit a rich redox chemistry, usually accompanied by structural reorganization during the redox processes often followed by ligand dissociation or association. The push-pull ligand 2,6-diguanidylpyridine (dgpy) stabilizes manganese in the oxidation states +II,… read more here.
Keywords: gas phase; chemistry; phase; manganese complexes ... See more keywords
Ligand-regulated three-photon AIE properties of manganese(II) complexes for photodynamic therapy.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt02410a
Abstract: Owing to the advantages of deeper penetration depth and lower biological damage, multi-photon AIE probes are widely used in the field of multi-photon therapy. We have developed a series of carbazole terpyridine manganese(II) complexes (MD1-MD3)… read more here.
Keywords: three photon; aie; photon aie; aie properties ... See more keywords
Thioether-NHC bidentate manganese complexes as efficient phosphine-free catalysts for hydrogenation at room temperature.
Sign Up to like & getrecommendations! Published in 2025 at "Chemical communications"
DOI: 10.1039/d4cc06627h
Abstract: A series of four original phosphine-free thioether-NHC manganese complexes have been synthesised and fully characterized. These complexes have been applied as efficient catalysts for the hydrogenation of alkenes and ketones at room temperature, with low… read more here.
Keywords: catalysts hydrogenation; manganese complexes; room temperature; phosphine free ... See more keywords
Questing for homoleptic mononuclear manganese complexes with monodentate O-donor ligands
Sign Up to like & getrecommendations! Published in 2024 at "Chemical Science"
DOI: 10.1039/d4sc00543k
Abstract: Compounds containing Mn–O bonds are of utmost importance in biological systems and catalytic processes. Nevertheless, mononuclear manganese complexes containing all O-donor ligands are still rare. Taking advantage of the low tendency of the pentafluoroorthotellurate ligand… read more here.
Keywords: questing homoleptic; manganese complexes; homoleptic mononuclear; mononuclear manganese ... See more keywords
Computational insight into manganese(II) complexes comprising macrocyclic ligands for magnetic resonance imaging.
Sign Up to like & getrecommendations! Published in 2025 at "Dalton transactions"
DOI: 10.1039/d5dt01381j
Abstract: The increasing interest in advances in the field of magnetic resonance imaging (MRI) and the promise of extensive development of Mn(II)-based MRI contrast agents have motivated us to investigate thoroughly manganese(II) complexes comprising macrocyclic ligands.… read more here.
Keywords: comprising macrocyclic; macrocyclic ligands; complexes comprising; resonance imaging ... See more keywords