Solvent effects on the spin crossover properties of manganese (III) (sal‐N‐1,5,8,12) complexes
Sign Up to like & getrecommendations! Published in 2024 at "European Journal of Inorganic Chemistry"
DOI: 10.1002/ejic.202400073
Abstract: The interplay of host−guest interactions and controlled modulation of spin‐crossover (SCO) behavior is one of the most exploited topics regarding data storage, molecular sensing, and optical technologies. This study examines the effect of solvents on… read more here.
Keywords: solvent effects; sal; spin crossover; effects spin ... See more keywords
Effect of density functional approximations on the calculated Jahn–Teller distortion in bis(terpyridine)manganese(III) and related compounds
Sign Up to like & getrecommendations! Published in 2024 at "Journal of Molecular Modeling"
DOI: 10.1007/s00894-023-05812-0
Abstract: Context Bis(terpyridine)manganese(III) exhibits Jahn–Teller distortion due to the inequivalent occupation of the degenerate e _ g orbitals of this high-spin d^4 pseudo octahedral complex. Due to the spatially constrained nature of the terpyridine ligand, the… read more here.
Keywords: jahn teller; bis terpyridine; terpyridine; terpyridine manganese ... See more keywords
A novel manganese(III)-peroxo complex bearing a proline-derived pentadentate aminobenzimidazole ligand
Sign Up to like & getrecommendations! Published in 2018 at "Chinese Chemical Letters"
DOI: 10.1016/j.cclet.2018.04.036
Abstract: Abstract Manganese(III)-peroxo complexes are invoked as key intermediates in the enzymatic cycles of Mn-containing enzymes, and the synthesis of reactive manganese(III)-peroxo complexes with rationally designed ligand has been of great interest in the communities of… read more here.
Keywords: manganese iii; pentadentate aminobenzimidazole; aminobenzimidazole ligand; peroxo complex ... See more keywords
Syntheses, molecular structures, and spectroscopic properties of manganese(II)/(III) complexes with tetraphenylimidodiphosphinato and bi-pyridine or salicylaldehyde ligands
Sign Up to like & getrecommendations! Published in 2020 at "Inorganica Chimica Acta"
DOI: 10.1016/j.ica.2019.119298
Abstract: Abstract Treatment of [Mn(CH3COO)2·4H2O] with two equivalents of K[N(Ph2PO)2] in the presence of one equivalent of 2,2′-bipyridine (bpy) or 5,5′-dimethyl-2,2′-bipyridine(dmbpy) in ethanol resulted in the formation of the mono-nuclear manganese(II) complexes [Mn{η1 O N(Ph2PO)2}{N(Ph2PO)2}(EtOH)(bpy)] (1)… read more here.
Keywords: manganese iii; molecular structures; ph2po; salicylaldehyde ... See more keywords
Studies on structural and optical properties of thermally evaporated nanocrystalline thin films of meso-Tetraphenylporphyrin manganese(III) chloride
Sign Up to like & getrecommendations! Published in 2018 at "Journal of Luminescence"
DOI: 10.1016/j.jlumin.2018.03.036
Abstract: Abstract Thin films of meso-Tetraphenylporphyrin manganese(III) chloride (MnTPPCl) were prepared by conventional thermal deposition technique, under vacuum (10−4 Pa), on glass and quartz substrates. X-ray diffraction (XRD) technique, Fourier-transform Infrared (FT-IR) technique and scanning electron… read more here.
Keywords: tetraphenylporphyrin manganese; manganese iii; iii chloride; thin films ... See more keywords
Thiosemicarbazide-based iron(III) and manganese(III) complexes. Structural, electrochemical characterization and antioxidant activity
Sign Up to like & getrecommendations! Published in 2019 at "Polyhedron"
DOI: 10.1016/j.poly.2019.114130
Abstract: Abstract New iron(III) and manganese(III) complexes were synthesized by the condensation of 1-phenyl-1,3-butanedione-S-propyl-thiosemicarbazone (1) with salicylaldehyde in the presence of iron(III) or manganese(II) ions. The complexes were characterised by analytical and spectroscopic methods. X-ray analysis… read more here.
Keywords: iii; manganese iii; iii complexes; iron iii ... See more keywords
The Full d3-d5 Redox Series of Mononuclear Manganese Complexes: Geometries and Electronic Structures of [Mn(dgpy)2]n.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c01680
Abstract: Although manganese ions exhibit a rich redox chemistry, redox processes are often accompanied by structural reorganization and a high propensity for ligand substitution, so that no complete structurally characterized manganese(II,III,IV) complex series without significant ligand… read more here.
Keywords: series; manganese iii; chemistry; dgpy ... See more keywords
Manganese(III) Nitrate Complexes as Bench-Stable Powerful Oxidants.
Sign Up to like & getrecommendations! Published in 2024 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.4c03411
Abstract: We report herein a convenient one-pot synthesis for the shelf-stable molecular complex [Mn(NO3)3(OPPh3)2] (2) and describe the properties that make it a powerful and selective one-electron oxidation (deelectronation) reagent. 2 has a high reduction potential… read more here.
Keywords: bench stable; stable powerful; nitrate complexes; complexes bench ... See more keywords
Keto-Enol Tautomerization Triggers an Electrophilic Aldehyde Deformylation Reaction by a Nonheme Manganese(III)-Peroxo Complex.
Sign Up to like & getrecommendations! Published in 2017 at "Journal of the American Chemical Society"
DOI: 10.1021/jacs.7b10033
Abstract: Oxygen atom transfer by high-valent enzymatic intermediates remains an enigma in chemical catalysis. In particular, manganese is an important first-row metal involved in key biochemical processes, including the biosynthesis of molecular oxygen (through the photosystem… read more here.
Keywords: manganese iii; mechanism; aldehyde deformylation; reaction ... See more keywords
The molecular and supramolecular aspects in mononuclear manganese(iii) Schiff-base spin crossover complexes.
Sign Up to like & getrecommendations! Published in 2017 at "Dalton transactions"
DOI: 10.1039/c7dt01718a
Abstract: Manganese(iii) hexadentate Schiff base complexes ([Mn(sal-N-1,5,8,12)]Y·S, Y = AsF6 (1); Y = SbF6 (2); Y = NO3, S = C2H5OH (3) and Y = Cl (4)) have been investigated to determine the impact of anion… read more here.
Keywords: manganese iii; spin crossover; schiff base;
Manganese(iii) acetate-mediated activation of C-H bonds of weak CH-acids; addition of o-carborane, its derivatives, and some other CH-acids to [60]-fullerene.
Sign Up to like & getrecommendations! Published in 2019 at "Dalton transactions"
DOI: 10.1039/c8dt04565h
Abstract: o-Carborane, 9-I-o-carborane, 1-Me-o-carborane, and several other CH-acids, 9H-fluorene, 2-Br-9H-fluorene, and trimethylsylylacetylene, have been shown to react with C60 affording their monoadducts with fullerene, the reaction being mediated by Mn(OAc)3·2H2O. In the case of o-carborane, when… read more here.
Keywords: manganese iii; c60; carborane; iii acetate ... See more keywords