Electrochemical behaviour and analytical applications of a manganese porphyrin – silica hybrid film prepared by pulsed laser deposition
Sign Up to like & getrecommendations! Published in 2020 at "Journal of Electroanalytical Chemistry"
DOI: 10.1016/j.jelechem.2020.114127
Abstract: Abstract Hybrid nanomaterials can have superior properties in comparison with individual components, sometimes greatly improving their optoelectronic activity. For this reason, modified carbon electrodes were obtained using a hybrid material composed of 5,10,15,20-tetra(4-tolyl)porphyrinato manganese (III)… read more here.
Keywords: silica hybrid; manganese porphyrin; porphyrin; hybrid film ... See more keywords
Biomimetic oxidation of cyclic and linear alkanes: high alcohol selectivity promoted by a novel manganese porphyrin catalyst
Sign Up to like & getrecommendations! Published in 2017 at "New Journal of Chemistry"
DOI: 10.1039/c6nj03072f
Abstract: A novel third-generation metalloporphyrin, chloro-5,10,15,20-tetrakis-(3′-bromine-4′-methoxyphenyl)-2,3,7,8,12,13,17,18-octabromoporphyrinatomanganese(III), [MnIIIBr12T4(-OMe)PPCl], designated as MnBr12Por, was synthesized and characterized. The catalytic activity of the new manganese porphyrin was investigated in the oxidation of cyclohexane, adamantane and n-hexane by iodosylbenzene (PhIO) or… read more here.
Keywords: manganese porphyrin; oxidation; catalyst; phio ... See more keywords
The Use of Thiocyanate Formulations to Create Manganese Porphyrin Antioxidants That Supplement Innate Immunity
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DOI: 10.3390/antiox11071252
Abstract: The innate immune response to infection results in inflammation and oxidative damage, creating a paradox where most anti-inflammatory and antioxidant therapies can further suppress an already inadequate immune response. We have previously reported the beneficial… read more here.
Keywords: mnp; scn; manganese porphyrin; innate immunity ... See more keywords
Manganese Porphyrin-Based SOD Mimetics Produce Polysulfides from Hydrogen Sulfide
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DOI: 10.3390/antiox8120639
Abstract: Manganese-centered porphyrins (MnPs), MnTE-2-PyP5+ (MnTE), MnTnHex-2-PyP5+ (MnTnHex), and MnTnBuOE-2-PyP5+ (MnTnBuOE) have received considerable attention because of their ability to serve as superoxide dismutase (SOD) mimetics thereby producing hydrogen peroxide (H2O2), and oxidants of ascorbate and… read more here.
Keywords: sod mimetics; manganese porphyrin; pyp5; porphyrin based ... See more keywords
Aerobic Epoxidation of Low-Molecular-Weight and Polymeric Olefins by a Supramolecular Manganese Porphyrin Catalyst
Sign Up to like & getrecommendations! Published in 2019 at "Catalysts"
DOI: 10.3390/catal9020195
Abstract: We report on the highly efficient epoxidation of low-molecular-weight and polymeric olefins catalyzed by a supramolecular manganese porphyrin complex using molecular oxygen as an oxidant and an aldehyde as a co-reductant. At ambient temperature and… read more here.
Keywords: low molecular; supramolecular manganese; porphyrin; epoxidation low ... See more keywords