Recent advances in the practical use of the redox properties of manganese porphyrins
Sign Up to like & getrecommendations! Published in 2021 at "Journal of Organometallic Chemistry"
DOI: 10.1016/j.jorganchem.2021.121880
Abstract: Abstract Porphyrins can stabilize unusual oxidation states of a transition metal when form complexes with the one. The stable oxidation states of manganese in such organometallic compounds are +3 and +5. Due to the rich… read more here.
Keywords: redox properties; advances practical; recent advances; manganese porphyrins ... See more keywords
Tetracationic and Tetraanionic Manganese Porphyrins: Electrochemical and Spectroelectrochemical Characterization.
Sign Up to like & getrecommendations! Published in 2017 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.7b00732
Abstract: The electrochemistry and spectroelectrochemistry of four tetrapositively charged and two tetranegatively charged porphyrins were characterized in two nonaqueous solvents (dimethyl sulfoxide and N,N-dimethylformamide) containing 0.1 M tetra-n-butylammonium perchlorate. The tetrapositively charged compounds are represented by… read more here.
Keywords: reduction; manganese porphyrins; pyridinium groups; pyridinium ... See more keywords