Allosteric Regulation in Carbon Monoxide (CO) Release: Anion Responsive CO-Releasing Molecule (CORM) Derived from (Terpyridine)phenol Manganese Tricarbonyl Complex with Colorimetric and Fluorescence Monitoring.
Sign Up to like & getrecommendations! Published in 2019 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.9b00984
Abstract: A new CO-releasing terpyridine based manganese(I) tricarbonyl complex, [MnBr(CO)3(terpy-C6H4OH)] (1·Mn-OH) functioning via light has been reported. For the first time, we have demonstrated the allosteric regulation concept to control the CO-releasing properties of a CO-releasing… read more here.
Keywords: allosteric regulation; manganese tricarbonyl; releasing molecule; tricarbonyl complex ... See more keywords
Insights into the Fluxional Processes of Monomethylcyclohexenyl Manganese Tricarbonyl
Sign Up to like & getrecommendations! Published in 2023 at "Molecules"
DOI: 10.3390/molecules28073232
Abstract: Multiple fluxional processes of 6-monomethylcyclohexenylmanganese tricarbonyl [(6-MeC6H8)Mn(CO)3, complex 1] and 5-monomethylcyclohexenylmanganese tricarbonyl [(5-MeC6H8)Mn(CO)3, complex 2] have been explored using density functional theory (DFT) computations. The contributions of four agostomers—1, 2, 3, and 4—to the (MeC6H8)Mn(CO)3… read more here.
Keywords: monomethylcyclohexenyl manganese; processes monomethylcyclohexenyl; tricarbonyl; manganese tricarbonyl ... See more keywords