Manipulating Spin Transition To Achieve Switchable Multifunctions.
Sign Up to like & getrecommendations! Published in 2019 at "Accounts of chemical research"
DOI: 10.1021/acs.accounts.9b00049
Abstract: The spin transition of metal ions involves interconversion between electron configurations exhibiting considerably different functions and plays a substantial role in the chemical, physical, and biological fields. The photoinduced spin transition offers a promising approach… read more here.
Keywords: spin transition; transition; manipulating spin; photoinduced spin ... See more keywords
Manipulating the Spin State of Fe Sites via Fe-O-Si Bridge Bonds for Enhanced Polysulfide Redox Kinetics in the Li-S Battery.
Sign Up to like & getrecommendations! Published in 2022 at "Inorganic chemistry"
DOI: 10.1021/acs.inorgchem.2c02897
Abstract: Transition metals with 3d unoccupied orbitals have superior catalytic activity, but inherent high spin suppresses their adsorption capability, leading to sluggish polysulfide conversion kinetics for Li-S batteries. Herein, we provide Fe-O-Si bridge bonds to manipulate… read more here.
Keywords: bridge; spin state; state sites; battery ... See more keywords
Manipulating the spin crossover behaviour in a series of cyanide-bridged {FeIII2FeII2} molecular squares through NCE- co-ligands.
Sign Up to like & getrecommendations! Published in 2022 at "Dalton transactions"
DOI: 10.1039/d2dt00058j
Abstract: Manipulating the transition temperature (T1/2) of spin-crossover (SCO) complexes capable of fulfilling practical criteria through different synthetic strategies is one of the main focuses in the field of molecular magnetism. The reaction of the tricyanometallate… read more here.
Keywords: nce ligands; crossover behaviour; spin crossover; manipulating spin ... See more keywords