Mapping Bridge Conformational Effects on Electronic Coupling in Mo2-Mo2 Mixed-Valence Systems.
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DOI: 10.1021/acs.inorgchem.8b01056
Abstract: The large bridging ligand 9,10-anthracenedicarboxylate and its thiolated derivatives have been employed to assemble two dimolybdenum complex units and develop three Mo2 dimers, [Mo2(DAniF)3]2(μ-9,10-O2CC14H8CO2), [Mo2(DAniF)3]2(μ-9,10-OSCC14H8COS), and [Mo2(DAniF)3]2(μ-9,10-S2CC14H8CS2) (DAniF = N, N'-di( p-anisyl)formamidinate), for the study… read more here.
Keywords: mapping bridge; electronic coupling; effects electronic; mixed valence ... See more keywords