Markovnikov Hydrosilylation of Alkenes: How an Oddity Becomes the Goal
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DOI: 10.1021/acscatal.8b03104
Abstract: Over the years, hydrosilylation of terminal alkenes has emerged as one of the most prominent applications of homogeneous catalysis. While most of the relevant reports concern β-selective hydrosilylation, yielding linear products which are of industrial… read more here.
Keywords: markovnikov hydrosilylation; becomes goal; hydrosilylation alkenes; oddity becomes ... See more keywords
Asymmetric Copper Hydride-Catalyzed Markovnikov Hydrosilylation of Vinylarenes and Vinyl Heterocycles
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DOI: 10.1021/jacs.6b13029
Abstract: We report a highly enantioselective CuH-catalyzed Markovnikov hydrosilylation of vinylarenes and vinyl heterocycles. This method has a broad scope and enables both the synthesis of isolable silanes and the conversion of crude products to chiral… read more here.
Keywords: markovnikov hydrosilylation; hydrosilylation vinylarenes; vinyl heterocycles; catalyzed markovnikov ... See more keywords
Iridium-catalyzed Markovnikov hydrosilylation of terminal alkynes achieved by using a trimethylsilyl-protected trihydroxysilane
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DOI: 10.1038/s42004-019-0206-4
Abstract: Developing efficient strategies for Markovnikov hydrosilylation of alkynes is still an important goal. The steric and electronic properties of hydrosilanes are key factors in controlling selectivity in these reactions. Here by using a trimethylsilyl-protected trihydroxysilane,… read more here.
Keywords: markovnikov hydrosilylation; iridium; terminal alkynes; hydrosilylation terminal ... See more keywords
Phenanthroline-imine ligands for iron-catalyzed alkene hydrosilylation
Sign Up to like & getrecommendations! Published in 2022 at "Chemical Science"
DOI: 10.1039/d1sc06727c
Abstract: Iron-catalyzed organic reactions have been attracting increasing research interest but still have serious limitations on activity, selectivity, functional group tolerance, and stability relative to those of precious metal catalysts. Progress in this area will require… read more here.
Keywords: iron; hydrosilylation; iron catalyzed; iron catalysts ... See more keywords