Copper-Catalyzed Transfer Markovnikov Hydrothiolation of Alkenes.
Sign Up to like & getrecommendations! Published in 2025 at "Organic letters"
DOI: 10.1021/acs.orglett.5c02764
Abstract: A copper(II) triflate catalyzed transfer hydromethylthiolation of alkenes has been developed using commercially available and easy-to-handle β-methylthioketone as the methanethiol donor under air. This method exclusively provides Markovnikov products. The reaction demonstrates a broad substrate… read more here.
Keywords: markovnikov hydrothiolation; transfer; hydrothiolation alkenes; copper catalyzed ... See more keywords